Class 12 Chemistry NCERT Exemplar Chapter 6: Higher Order Thinking Skills (HOTS) Questions
Some Class 12 chemistry chapter 6 questions and answers are given below that will help you tackle complex problems. The questions below will help you evaluate your understanding of the concepts.
Question 1: Which among the following is used to reduce$\mathrm{TiCl}_4$ to Ti?
(1) C
(2) Al
(3) Mg
(4) H2
Answer: Titanium dioxide is reacted with chlorine to form titanium tetrachloride, which is then reacted with magnesium to remove the chlorine and leave behind the pure metal.
In Kroll's process for titanium, Mg is used as a reducing agent
$
\mathrm{TiCl}_4+2 \mathrm{Mg} \rightarrow 2 \mathrm{MgCl}_2+\mathrm{Ti}
$
This represents the reduction of titanium tetrachloride $\left(\mathrm{TiCl}_4\right)$ with magnesium to produce titanium metal and magnesium chloride.
Hence, the correct answer is option (3).
Question 2: Roasting of sulphides gives the gas ‘A’ as a by- product. ‘A’ is a colourless gas with choking smell of burnt sulphur and causes great damage to respiratory organs as a result of acid rain. Its aqueous solution is acidic acts as a reducing agent and its acid is known only in solution. The gas ‘A’ is
(1) $\mathrm{SO}_2$
(2) $\mathrm{CO}_2$
(3) $\mathrm{SO}_3$
(4) $\mathrm{H}_2 \mathrm{~S}$
Answer:
Gas ' $A$ ' is Sulphur dioxide $\mathrm{SO}_2 . \mathrm{SO}_2$ is a colourless gas which can cause damage to respiratory organs. Its aqueous solution is acidic
$
\mathrm{SO}_2+\mathrm{H}_2 \mathrm{O} \rightarrow \mathrm{H}_2 \mathrm{SO}_3
$
$\mathrm{H}_2 \mathrm{SO}_3$ is sulphurous acid.
Hence, the correct answer is option (1).
Question 3: The following reaction occurs in the Blast furnace, where iron ore is reduced to iron metal
$\mathrm{Fe}_2 \mathrm{O}_{3(\mathrm{~s})}+3 \mathrm{CO}_{(\mathrm{g})} \rightleftharpoons \mathrm{Fe}_{(\mathrm{l})}+3 \mathrm{CO}_{2(\mathrm{~g})}$
Using the Le-chatelier's principle, predict which one of the following will not disturb the equilibrium.
(1) Addition of $\mathrm{Fe}_2 \mathrm{O}_3$
(2) Addition of $\mathrm{CO}_2$
(3) Removal of CO
(4) Removal of $\mathrm{CO}_2$
Answer:
When solid is added there is no effect on equilibrium. So, the addition of $\mathrm{Fe}_2 \mathrm{O}_3$ will does not disturb the equilibroum.
Hence, the answer is option (1).
Question 4: Identify the incorrect pair from the following :
(1) Carnallite $-\mathrm{KCl} \cdot \mathrm{MgCl}_2, 6 \mathrm{H}_2 \mathrm{O}$
(2) Cryolite $-\mathrm{Na}_3 \mathrm{AlF}_6$
(3) Fluroapatite - $3 \mathrm{Ca}_3\left(\mathrm{PO}_4\right)_2 \cdot \mathrm{CaF}_2$
(4) Fluorspar - $\mathrm{BF}_3$
Answer:
Fluorspar, also known as fluorite, is a mineral composed of calcium fluoride (CaF₂).
Hence, the answer is the option (4).
Question 5: Which among the following forms a slag from P2O5 impurity during the extraction of iron?
(1) $\mathrm{CaSiO}_3$
(2) $\mathrm{Ca}_3\left(\mathrm{PO}_4\right)_2$
(3) $\mathrm{Fe}_3\left(\mathrm{PO}_4\right)_2$
(4) $\mathrm{FeSiO}_3$
Answer:
During the extraction of iron, slag formed from $\mathrm{P}_2 \mathrm{O}_5$ impurities is $\mathrm{Ca}_3\left(\mathrm{PO}_4\right)_2$
$\mathrm{P}_2 \mathrm{O}_5+3 \mathrm{CaO} \rightarrow \mathrm{Ca}_3\left(\mathrm{PO}_4\right)_2$
Hence, the answer is the option (1).
Approach to Solve Questions of Chapter 6 Effectively
To effectively solve questions from this chapter you can follow the points below to build a good strategy.
1. Identify the kind of question, such as
Conceptual- These are based on definitions or theory.
Reaction-based - These involve chemical equations.
Process-based- These are related to steps in metallurgy (e.g., roasting, smelting).
Application-based- It comes from real-life uses or comparisons.
The NCERT Exemplar Class 12 Chemistry Solutions Chapter 6 will help you understand these concepts better.
2. Revising the concepts is basic to attempt questions. Some of the important concepts are
Occurrence of metals- Ores and minerals.
Concentration of ores- Gravity separation, froth flotation, magnetic separation.
Extraction methods-
- Roasting and calcination
- Reduction (using C, CO, Al, etc.)
- Electrolytic reduction
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Refining methods like distillation, liquation, electrolytic refining, zone refining. Also,thermodynamic principles like Ellingham diagrams are important for examination purpose.
3. Refer to the NCERT in-text questions and exercises. You can also follow previous year questions as to get a clear idea of the exam pattern. You can get these type of questions in the NCERT Class 12 solutions available on our website.
4. Follow NCERT solved examples to know the correct way to solve the questions. The answer should contain the key points of the related concepts. Follow the NCERT solutions for detailed explanations.
Formulas And Equations for NCERT Exemplar Class 12 Chemistry Chapter 6
The following are the important formulas covered in the Class 12 NCERT Chemistry chapter 6.
1. Ellingham Equation (Qualitative form)
$
\Delta G=\Delta H-T \Delta S
$
2. Extraction of Iron (from Hematite)
$
\mathrm{Fe}_2 \mathrm{O}_3+3 \mathrm{CO} \rightarrow 2 \mathrm{Fe}+3 \mathrm{CO}_2
$
3. Extraction of Copper (from $\mathrm{Cu}_2 \mathrm{~S}$ )
$
\begin{aligned}
2 \mathrm{Cu}_2 \mathrm{~S}+3 \mathrm{O}_2 & \rightarrow 2 \mathrm{Cu}_2 \mathrm{O}+2 \mathrm{SO}_2 \\
\mathrm{Cu}_2 \mathrm{~S}+\mathrm{Cu}_2 \mathrm{O} & \rightarrow 6 \mathrm{Cu}+\mathrm{SO}_2
\end{aligned}
$
4. Purification by Mond's Process (Nickel)
$
\begin{array}{ll}
\mathrm{Ni}+4 \mathrm{CO} \rightarrow \mathrm{Ni}(\mathrm{CO})_4 & (\text { at } 330 K) \\
\mathrm{Ni}(\mathrm{CO})_4 \rightarrow \mathrm{Ni}+4 \mathrm{CO} & (\text { at } 450 K)
\end{array}
$
5. Extraction of Zinc (from ZnO)
$
\mathrm{ZnO}+\mathrm{C} \rightarrow \mathrm{Zn}+\mathrm{CO}
$