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The structure of the atom is an important chapter in the Class 11 Chemistry subject. The understanding of the atom and its structure is very important for chemistry students. Structure of Atom Class 11 notes helps students to get the basic information about atoms. Structure of Atom class 11 notes act as a quick revision tool for students appearing for the examination. It will also boost their memory power.
class 11 chemistry chapter 2 notes also help to crack the NEET, JEE Main, etc. examinations. cbse class 11 chemistry ch 2 notes help students in getting high marks in the board examination. For quick revision students can go through chemistry class 11 chapter 2 notes pdf .
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Structure of Atom
Discovery of electron discharge tube experiment
In the discharge tube experiment conducted by William Crookes, the conduction of electricity through gases at low pressure is studied. The discharge tube is a cylindrical hard glass tub about 60 cm in length. Both ends of the discharge are to be sealed and fitted with the two metal electrodes.
Only at very low pressure and high voltages electric discharge through the gases is observed. The pressure of a gas can be adjusted by using evacuation. Under the supply of high voltage across the electrodes current starts flowing and the stream of particles are moving from the tuber in the negative electrode to the positive electrode. And it is called cathode rays.
They travel in a straight line.
Cathode rays begin from the cathode and then move towards the anode.
They are invisible but can be made visible with the help of materials like a fluorescent or a Phosphorescent.
Since under the supply of electric charge they are moved to the positive charge which indicates that cathode rays consist of negatively charged particles.
The properties of cathode rays do not depend upon the material of the electrode in which it is used and the nature of gases that are present in the cathode ray tube.
Experimentally JJ Thomson determined the charge-to-mass ratio of the electrons. According to Thomson’s experiment, the amount of deviation for a particle from their path under the presence of an electric and a magnetic field depends upon
Deflection tends to be higher when the magnitude of the charge is higher for the particles.
When the mass of a particle is lighter the deflection will be greater.
With the increase of voltage across the electrodes for with the increase of the strength of the magnetic field the deflection of electrons will also rise.
Thomson determined the value of eme=1.758820×1011Ckg-1
Where a mass of the electron and is the magnitude of charge.
Charge on the Electron
Oil drop experiment conducted by R A Milliken finds out the charge on the electron.
Charge of an electron=-1.6022×10-19C
Mass of electronee/me=1.6022×10-19C/1.758820×1011Ckg-1=9.1094×10-31kg
Discovery of Proton Anode Rays
Goldstein conducted another experiment with the help of a perforated cathode ray tube. A new type of eraser passes through the perforation of the card order by reducing the pressure and it is moving just the opposite direction as that of the cathode rays. These are named canal rays or anode rays.
Properties of anode rays
The magnitude of the positive charge of anode rays depends upon the nature of the gas that is present in the tube.
It also depends on the gas for the value charge to mass ratio.
The behavior of anode rays is just opposite to the cathode rays and the magnetic and electric field.
Thomson Model of The Atom
JJ Thomson proposed a structure for an atom that can be regarded as a sphere of an approximate radius carrying a positive charge due to protons and in which the negatively charged electrons are embedded into it. Thereby the atom can be visualized as a pudding for a cake positively charged with electrons in it. And the mass of atoms evenly spread over the atom. Although it was able to explain the overall neutrality of the other it cannot explain the result of the scattering experiment conducted by Rutherford.
JJ Thomson's model of atom
Rutherford Alpha Particle Scattering Experiment
By the use of a thin foil of metals like gold silver platinum with a beam of fast-moving Alpha particles Rutherford conducted some scattering experiments. And the thin gold foil has a fluorescent screen surrounding it. Whenever a particle struck the screen a flash of light was produced.
Rutherford alpha particle scattering experiment
One of the characteristics of the Rutherford Alpha scattering experiment is,
Most of the Alpha particles do not undergo any deflection only a few of them undergo deflection through some small angles.
Only a few deflectors back.
Based on these observations Rutherford concluded that since most of the Alpha particles passed through the foil without taking place any deflection there is much space in the atom. Since only a small question underwent deflection so the positive charger is a very small volume concentrated at the center. And the small portion of the atom is named the nucleus.
Atomic Number
The number of protons present in the nucleus is referred to as the atomic number. For example, the number of protons in a sodium atom is 11 and also the atomic number of sodium is 11. For maintaining electrical neutrality the number of electrons in an atom is equal to the number of protons.
Mass Number
The sum of the number of protons and neutrons present in a nucleus together is called the mass number.
The element that is having the same atomic number but the different mass number is isotopes. 1H1, 1H2, 1H3. And the element that is processing the same mass number but the different atomic number is isobars. 6C14, 7N14.
Development Leading to Bohr's Model of The Atom
Radiation causes wavelike and particle-like properties which means that it is having a dual character
The atomic spectra can be explained only by assuming the quantum state electronic energy levels in atoms.
Black Body Radiation
The ideal body that has the ability to emit and absorb all frequencies is a black body. And the corresponding radiation emitted by a black body is black body radiation.
Planck's Quantum Theory
Max Planck put forward a theory for explaining the phenomenon of blackbody radiation and the photoelectric effect. The theory focuses on
The radiant energy absorbed or omitted is in the form of small pockets of energy and these small pockets of energy are quantum.
The energy of each Quantum is directly proportional to the frequency of the radiation emitted.
E= hv
Photoelectric Effect
When a beam of light passes on the surface of some metals electrons are emitted from the metal surface. This phenomenon is the photoelectric effect. And it has been observed that only photons of light of a particular frequency that is the threshold frequency can cause the photoelectric effect. The kinetic energy of the electron emitted from the surface of the metal is directly proportional to the frequency of the striking photons. And also when the intensity of the photon of the light is increasing more electrons are ejected.
Photoelectric effect
Dual Behavior of Electromagnetic Radiation
Light and other electromagnetic radiation consist of a dual nature. That is they have particle and wave-like properties. Radiations emitted with the matter show the properties of a particle lies by exhibiting propagation. Electrons also exhibit wave-particle duality.
Spectrum
When a light ray passes through a prism the wave which is having a short wavelength forms a colored band more than the one which is having a longer wavelength. These bands then spread to form a series of colored bands and are called the spectrum. The one which is deviated least is the one which is having the longest wavelength that is their red color.
Continuous spectrum
When white light is passed through a prism it will split seven different colored bands just like a rainbow and these colors are continuous and it is called the continuous spectrum.
Emission spectra
When radiation is emitted from a source and is then passed to a prism which is then received on a photographic plate it is called the emission spectra. The emission spectrum can be observed by heating a substance with a high temperature.
Line spectra
The vapors of some volatile substance when allowed to fall on the flame of a bunsen burner and which is further analyzed with the help of spectroscopy some specific colored lines appear on the photographic plate. And the colored lines differ for a different substance. Sodium emit yellow light while potassium emit violet light
Absorption spectra
A ray of light, when allowed to pass through the vapors of a substance and the transmitted light, is then allowed to strike a prism dark lines appear. The dark line represents that the radiations corresponding to them are absorbed by the substance. And the spectrum is called the absorption spectrum.
Line Spectrum of Hydrogen
In the discharge October under low pressure when an electric discharge is passed through the hydrogen gas light is emitted and is analyzed by spectroscopy The spectrum consisting of a large number of lines is obtained and the spectrum is called the hydrogen spectrum. The series of lines is named as Lyman series, Balmer series, Paschen series, Brackett series, and Pfund series.
Bohr's Model of An Atom
Bohr's model of the atom is based on Planck's Quantum theory. According to this model in an atom, the electron revolves around the nucleus in a definite circular path called the orbits. Each orbit has definite energy and it can be named as the energy levels. The energy orbits that are permitted for an electron are in which the angular momentum of the electron is an old multiple of h/2π. And when an electron is present in an orbit it neither losses nor absorbs energy it will remain in a constant form. But when energy is supplied to an electron it will jump into a higher energy state that is the excited state.
Achievements of Bohr's theory
It has been explained the stability of an atom.
It also helps for calculating the energy of an electron in a hydrogen atom and also for one-electron species.
Quantum Mechanical Model of The Atom
Theoretical science that deals with the study of the motion of microscopic objects that have both particle-like and wave-like properties.
The energy of an electron in an atom is in a quantized state.
Due to the wavelike properties of electrons, it will exist in the quantized electronic energy level.
The exact position and exact velocity of an electron in an atom cannot be found out simultaneously.
For an atomic orbital, it has a wave function
The square of the orbital wave function 2 is the probability of finding an electron.
Quantum numbers
As the atomic energy levels or the orbits are quantized that can be expressed in the terms of quantum number. Quantum numbers are;
Principal
Azimuthal
Magnetic
Spin
Notes for Class 11 Chemistry chapter 2 focuses on the main points regarding the structure of atoms. Structure of Atom Class 11 notes pdf download will help students by providing quick revision before going for the examination. CBSE Class 11 Chemistry chapter 2 notes will also give key points for students who wish to crack NEET and JEE MAIN exams. These notes will also help students in getting high marks in many competitive examinations. Structure of atoms Class 10 notes will make students study in the offline mode. cbse class 11 chemistry ch 2 notes is good source to boost the overall preparation.
NCERT Class 11 Chemistry Chapter 2 Notes |
A detailed explanation of the Bohr atom model is provided in the ch 2 chemistry class 11 notes.
It is cannot able to explain the atomic spectra of species containing more than one electron.
The fine structure of spectral lines does not explain the well.
The does not give any satisfactory explanation for the stark effect and Zeeman effect.
Do not follow the Heisenberg uncertainty principle.
According to Rutherford’s model of an atom, the positive charge is a very small region in an atom. And the small portion is named a nucleus. Surrounding the nucleus electrons are present and they move in a circular path called the orbit. The electrostatic force of attraction is holding the electrons and nucleus. A detailed view is provided in the chemistry class 11 chapter 2 notes pdf .
This topic is very important and compared to other topics it is easy to score good marks. The basic information regarding an atom that is proton, neutron, electron, and nucleus is very important for future studies too. further you can read the topics in ch 2 chemistry class 11 notes provided here.
John Dalton
A sphere of positively charged particles and electrons is embedded in it is an atom. In the Class 11, the Structure of Atom notes this topic is clearly explained.
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As per latest 2024 syllabus. Physics formulas, equations, & laws of class 11 & 12th chapters
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