NCERT Solutions for Class 11 Chemistry Chapter 7 (Exercise Questions)
Given below the detailed and accurate class 11 chemistry chapter 7 redox reactions question answer. These solutions will help in better concept clarity and exam preparation. NCERT Solutions for Class 11 is are prepared by experts in a very clear and comprehensive manner.
Question 7.1 Assign oxidation number to the underlined elements in each of the following species
$(a) NaH_{2}\bar{P}O_{4}$
$(b)NaH\bar{S}O_{4}$
$(c) H_{4}\bar{P_{2}}O_{7}$
$(d) K_{2}\bar{Mn}O_{4}$
$(e) Ca\bar{O_{2}}$
$(f) Na\bar{B}H_{4}$
$(g) H_{2}\bar{S_{2}}O_{7}$
$(h) KAl(\bar{S}O_{4})_{2}.12H_{2}O$
Answer :
O.N is the oxidation number
O.N of Oxygen( $O$ ) = -2 ( In case of peroxide and superoxide it wil be different ON)
O.N of hydrogen( $H$ )= +1 (In case of metalic hydride, -1)
O.N of sodium ( $Na$ ) = +1
O.N of aluminium ( $Al$ ) = +3
O.N of potassium ( $K$ )= +1
O.N of calcium ( $Ca$ ) = +2
In neutral compounds, the sum of O.N of all the atoms is zero.
(a) Let the O.N of P be x
$\therefore\:\:\:1\ast 1+2\ast 1+x+4\ast (-2) = 0 \Rightarrow x = +5$
(b) Let the O.N. of S be x
$\therefore \:\:1\ast 1 + 1\ast 1+x +4\ast (-2) = 0\Rightarrow x = +6$
(c) Let the O.N. of P be x
$\therefore \:\:4*1 +2*x +7*(-2) = 0 \Rightarrow x = +5$
(d) Let the O.N. of Mn be x
$\therefore \:\:2*1 + x + 4*(-2) = 0\Rightarrow x = +6$
(e) Let the O.N. of O be x
Ca is an alkaline earth metal, so its O.N. is +2
$\therefore \:\:1\ast 2 + 2\ast x = 0\Rightarrow x = -1$
(f) Let the O.N. of B be x
Note that in this, H exists as a hydride ion, H− so its O.N. is -1
$\therefore \:\:1*1+x+4*(-1) = 0 \Rightarrow x = +3$
(g) Let the O.N. of S be x
$\therefore \:\: 2*1 +2*x+7*(-2) =0 \Rightarrow x = +6$
(h) Let the O.N. of S be x
$\therefore \:\:1*1+1*3+[x+(-2)*4]*2 +12*[1*2+(-2)] = 0\Rightarrow x = +6$
Question 7.2 What are the oxidation numbers of the underlined elements in each of the following and how do you rationalise your results
$(a) K\underline{I}_{3}$
$(b) H_{2}\underline{S_{4}}O_{6}$
$(c) \underline{Fe}_{3}O_{4}$
$(d) \underline{C}H_{3}\underline{C}H_{2}OH$
$(e) \underline{C}H_{3}\underline{C}OOH$
Answer :
Solution-
O.N of potassium ( $K$ )= +1
O.N of hydrogen( $H$ )= +1 (In case of metalic hydride, -1)
O.N of Oxygen( $O$ ) = -2 ( In case of peroxide and superoxide, it will be different ON)
$(a) K\underline{I}_{3}$
1*1 + 3*x = 0
x = (-1/3)
average O. N. of $I$ is $-\frac{1}{3}$
But it is wrong because O.N. cannot be fractional. So let's try with the structure of $KI_{3}$
O.N of I = -1 (because a coordinate bond is formed between $I_{2}$ and I− ion. Hence, O.N of three I atoms are 0,0 and -1, O.N 0 in $I_{2}$ molecule and -1 in I− ion.)
$K^+(I-I\leftarrow I)^{-1}$
O.N of $I$ = -1 (because a coordinate bond is formed between $I_{2}$ and $I^{-}$ ion. Hence O. N of three $I$ atoms are 0,0 and -1, O.N 0 in $I_{2}$ molecule and -1 in $I^{-}$ ion.)
$(b) H_{2}\underline{S_{4}}O_{6}$
Assume O.N of S is x
$2*1 + 4*x + 6*(-2) = 0 \Rightarrow x=2.5$
Fractional O.N. is not possible, so try with structure -
![1594293130665]()
The two S atoms present in the middle has zero (0) O.N and other two have (+5) O.N [ -2 from the two O atoms and -1 from OH]
$(c) \underline{Fe}_{3}O_{4}$
If you calculate the oxidation number of Fe in $Fe_{3}O_{4}$ it would be 8/3 and however, O.N cannot be in fractional.
$Fe_{3}O_{4} \:\:\: is \:an\:equimolar \:mixture\: of \:(FeO)\: and \:(Fe_{2}O_{3})$ Here one iron atom has +2 O.N and the other two are of +3 O.N.
$(d) \bar{C}H_{3}\bar{C}H_{2}OH$
let assume carbon has x oxidation Number
So,[ x + 1(3) +x +1(2) +(-2)+1 = 0]
2x = - 4
x = - 2
In this molecule, two carbon atoms are present in different environments. Hence, they cannot have the same O.N. Thus, C exhibits the O.S. of -3 and -1.
![1594293648509]()
$(e) \bar{C}H_{3}\bar{C}OOH$
Suppose the oxidation number of Carbon is x.
If we calculate the O.N of x, we get x=0
However, 0 is the average O.N. of C atoms. In this molecule, two carbon atoms are present in different environments. Hence, they cannot have the same O.N. Thus, C exhibits the O.S of +3 and -3 and +2 in CH3COOH. This can be better understood by the structure-
![1594293781269]()
Here we can see that at right C, -3 O.N (-1 from OH and -2 from O atom) and in left C, +3 O.N(contribution from H atom only)
Question 7.3(a) Justify that the following reactions are redox reaction
$\mathrm{CuO}(s)+\mathrm{H}_2(g) \rightarrow \mathrm{Cu}(s)+\mathrm{H}_2 \mathrm{O}(g)$
Answer: Let us write the O.N. of each element
$\overset{\:\:2+\:\:-2}{CuO}\:+\:\overset{0}{H_{2}}\rightarrow \overset{0}{Cu}\:+ \:\overset{+1\:-2}{H_{2}O}$
Here, the O.N of Cu decreases from +2 to 0, i.e., CuO is reduced to Cu. Also, the O.N. of H increases from 0 to +1, i.e., H2 is oxidised to H2O. Hence, it is a redox reaction.
Question 7.3(b) Justify that the following reactions are redox reactions
$\mathrm{Fe}_2 \mathrm{O}_3(\mathrm{~s})+3 \mathrm{CO}(\mathrm{g}) \rightarrow 2 \mathrm{Fe}(\mathrm{s})+3 \mathrm{CO}_2(\mathrm{~g})$
Answer: Let us write the O.N. of each element
$\overset{\:\:+3\:\:-2}{Fe_{2}O_{3}}\:+ 3\overset{+2\:-2}{CO}\rightarrow 2\overset{0}{Fe}\:\:+$ $3\overset{+4\:\:-2}{CO_{2}}$
Here, the O.N. of Fe decreases from +3 to 0. Also, the O.N. of C increases from +2 to +4. Hence, it is a redox reaction.
Question 7.3(c) Justify that the following reactions are redox reaction
$4 \mathrm{BCl}_3(g)+3 \mathrm{LiAlH}_4(s) \rightarrow 2 \mathrm{~B}_2 \mathrm{H}_6(g)+3 \mathrm{LiCl}(s)+3 \mathrm{AlCl}_3(s)$
Answer: Let us write the O.N. of each element
$4\overset{+3\:\:-1}{BCl_{3}}\:\:+\:3\overset{+1\:\:+3\:\:-1}{LiAlH_{4}}\:\rightarrow\:2\overset{-3\:\:+1}{B_{2}H_{6}}\:\:+\:\:3\overset{+1\:-1}{LiCl}\:\:+\:3\overset{+3\:-1}{AlCl_{3}}$
Here, the O.N. of Fe decreases from +3 in BCl3 to –3 in B2H6. And, the O.N. of H increases from -1 in LiAlH4 to +1 in B2H6. Hence, it is a redox reaction.
Question 7.3(d) Justify that the following reactions are redox reaction
$2 \mathrm{~K}(\mathrm{~s})+\mathrm{F}_2(\mathrm{~g}) \rightarrow 2 \mathrm{KF}(\mathrm{s})$
Answer: We know that oxidation = loss of electrons by an atom
and reduction = gaining of e− by another atom
Here, K lose its electron and F accept it. Hence, it is a redox reaction
Question 7.3(e) Justify that the following reactions are redox reactions
$4 \mathrm{NH}_3(\mathrm{~g})+5 \mathrm{O}_2(\mathrm{~g}) \rightarrow 4 \mathrm{NO}(\mathrm{g})+6 \mathrm{H}_2 \mathrm{O}(\mathrm{g})$
Answer: Here, N (−3) → N (+2) oxidation reaction
and O (0) → O (−2) reduction reaction (oxidation state of oxygen is zero at molecular state )
Hence, it's a redox reaction
Question 7.4 Fluorine reacts with ice and results in a change
$\mathrm{H}_2 \mathrm{O}(\mathrm{s})+\mathrm{F}_2(\mathrm{~g}) \rightarrow \mathrm{HF}(\mathrm{g})+\mathrm{HOF}(\mathrm{g})$
Justify that this reaction is a redox reaction
Answer :
$\begin{array}{rcc}F_2 & \mathrm{HF} & \mathrm{HOF} \\ \text { Oxidation state of } F \rightarrow 0 & -1 & +1\end{array}$
Here, F is oxidised and reduced as well. So, it is a redox reaction.
Question 7.8 While sulphur dioxide and hydrogen peroxide can act as oxidising as well as reducing agents in their reactions, ozone and nitric acid act only as oxidants. Why?
Answer :
- Sulphur dioxide (SO2) here oxidation state of sulphur is +4, and the range of oxidation number of S is from -2 to +6. It means it can accept an electron and lose as well; therefore, it can behave as an oxidant and a reductant.
- In case of hydrogen peroxide $(H_{2}O_{2})$ oxidation state is -1, and the oxidation state of O can vary from 0 to -2. So it shows both oxidising and reducing properties.
- For $HNO_{3}$, Nitrogen has a +5 oxidation state and it varies from +5 to -3. So it only accepts electrons. The oxidation state of N only decreases. Hence, it acts as the only oxidant.
- And in case of $O_{3}$, the oxidation state of O is zero(0), and the range of oxidation number of O is 0 to -2. It only decreases in this case also so it acts as only an oxidant.
Question 7.9 Consider the reactions:
(a) $6 \mathrm{CO}_2(g)+6 \mathrm{H}_2 \mathrm{O}(l) \rightarrow \mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6(a q)+6 \mathrm{O}_2(g)$
(b) $\mathrm{O}_3(g)+\mathrm{H}_2 \mathrm{O}_2(l) \rightarrow \mathrm{H}_2 \mathrm{O}(l)+2 \mathrm{O}_2(g)$
Why is it more appropriate to write these reactions as :
(a) $6 \mathrm{CO}_2(g)+12 \mathrm{H}_2 \mathrm{O}(l) \rightarrow \mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6(a q)+6 \mathrm{H}_2 \mathrm{O}(l)+6 \mathrm{O}_2(g)$
(b) $\mathrm{O}_3(g)+\mathrm{H}_2 \mathrm{O}_2(l) \rightarrow \mathrm{H}_2 \mathrm{O}(l)+\mathrm{O}_2(g)+\mathrm{O}_2(g)$
Also, suggest a technique to investigate the path of the above (a) and (b) redox reactions.
Answer :
(a) In the photosynthesis process-
Step 1- the liberation of $O_{2}$ and $H_{2}$ --> $2H_{2}O\rightarrow O_{2}+2H_{2}$
Step-2 The $H_{2}$ produced in above reduces the $CO_{2}$ into glucose $(C_{6}H_{12}O_{6})$ and water $(H_{2}O)$
$6CO_{2}+12H_{2}\rightarrow C_{6}H_{12}O_{6}+6H_{2}O$
So, the final net reaction is
$2H_{2}O\rightarrow CO_{2}+2H_{2}]*6\\+6CO_{2}+12H_{2}\rightarrow C_{6}H_{12}O_{6}+6H_{2}O\\$
------------------$\\6CO_{2}+12H_{2}O\rightarrow C_{6}H_{12}O_{6}+6H_{2}O$
It is more appropriate to write the reaction as above because the water $(H_{2}O)$ molecule also produced in the photosynthesis reaction.
The path of reaction can be investigated by using the radioactive $H_{2}O^{18}$ instead of $(H_{2}O)$
(b)
$\\O_{3}(g)\rightarrow O_{2}(g)+O(g)\\ H_{2}O_{2}(l)+O(g)\rightarrow H_{2}O(l)+O_{2}(g)\\$ ---------------$\\ H_{2}O_{2}(l)+O_{3}(g)\rightarrow H_{2}O(l)+O_{2}(g)+O_{2}(g)$ (the final net reaction)
Dioxygen is produced from both steps, one from the decomposition of ozone ( $O_{3}$ ) and the other is from the reaction of hydrogen peroxide with(O)
- The path of the reaction can be investigated by using $O^{18}_{3}/ H_{2}O^{18}$.
Question 7.12(a) How do you count for the following observations?
Though alkaline potassium permanganate and acidic potassium permanganate both are used as oxidants, yet in the manufacture of benzoic acid from toluene, we use alcoholic potassium permanganate as an oxidant. Why? Write a balanced redox equation for the reaction.
Answer :
Alcohol and KMnO4 both are polar in nature and alcohol is homogenous with toluene because both are organic compounds. So the reaction is faster in the homogeneous medium than in the heterogeneous medium. And hence all the compounds react at a faster rate.
Chemical equation-
$C_{6}H_{6}CH_{3}+MnO_{4}^{-}(alc.)\rightarrow C_{6}H_{6}COO^{-}+MnO_{2}+H_{2}O(l)+OH^{-}(aq)$
Question 7.12(b) How do you count for the following observations?
When concentrated sulphuric acid is added to an inorganic mixture containing chloride, we get colourless pungent pungent-smelling gas HCl, but if the mixture contains bromide, then we get red vapour of bromine. Why?
Answer :
- Concentrated sulphuric acid is added to an inorganic mixture containing chloride-
$2NaCl\:+\:2H_{2}SO_{4}\rightarrow \: 2NaHSO_{4}\:+\: 2HCl$
HCl is a weak reducing agent, and it cannot reduce $H_{2}SO_{4}$ to $SO_{2}$ that's why we get colourless pungent pungent-smelling gas HCl.
- Concentrated sulphuric acid is added to an inorganic mixture containing bromide-
$2NaBr\:+\:2H_{2}SO_{4}\rightarrow \: 2NaHSO_{4}\:+\: 2HBr$
$2HBr + H_{2}SO_{4}\:\rightarrow \:Br_{2} ( Red \:Vapour)\:+\:SO_{2}\:+\:2H_{2}O$
When conc. Sulphuric acid is added to an inorganic mixture containing bromide initially, it produces $HBr$ and it is a strong reducing agent so it reduces $H_{2}SO_{4}$ to $SO_{2}$ with the evolution of a red vapour of bromine.
Question 7.15 Justify giving reactions that among halogens, fluorine is the best oxidant and among hydrohalic compounds, hydroiodic acid is the best reductant.
Answer :
part(i)
Fluorine can oxidise other halogen ions. On the other hand $Br_{2},I_{2},Cl_{2}$ cannot oxidize
$2F^{-} \rightarrow F_{2}$
$F_{2}+2I^{-}\rightarrow 2F^{-}+I_{2}$
$F_{2}+2Br^{-}\rightarrow 2F^{-}+Br_{2}$
$F_{2}+2Cl^{-}\rightarrow 2F^{-}+Cl_{2}$
And hence we say that fluorine is the better oxidant among halogens.
part(ii)
$HI$ & $HBr$ are able to reduce $H_{2}SO_{4}\rightarrow SO_{2}$ but $HCl,HF$ are unable to reduce sulphuric acid.
So here we can say that $HI$ & $HBr$ are better reducing agents than $HCl,HF$ .
Again $I^{-}$ can only able to reduce $Cu^{2+}\rightarrow Cu^{+}$ but $Br^{-}$ cannot.
$4I^{-}+2Cu^{2+}\rightarrow Cu_{2}I_{2}+I_{2}$
Hence, among hydrohalic compounds, hydroiodic acid is the best reducing agent.
Question 7.16 Why does the following reaction occur?
$XeO_{6}^{4-}(aq)+2F^{-}(aq)+6H^{+}(aq)\rightarrow XeO_{3}(g)+F_{2}(g)+3H_{2}O(l)$
What conclusion about the compound $Na_{4}XeO_{6}$ (of which $XeO_{6}^{4-}$ is a part) can be drawn from the reaction?
Answer :
We conclude that the oxidation state of Xenon changes from +8 to +6
$XeO_{6}^{4-} (+8)\rightarrow XeO_{3}(+6)$
and the oxidation state of F changes from -1 to 0
$F^{-}(-1)\rightarrow F_{2}(0)$
$Na_{4}XeO_{6}$ is reduced by accepting an electron.
It is a stronger oxidising agent than F
Question 7.17(a) Consider the reactions:
(a) $H_{3}PO_{2}(aq)+4AgNO_{3}(aq)+2H_{2}O(l)\rightarrow H_{3}PO_{4}(aq)+4Ag(s)+4HNO_{3}(aq)$
$(b)H_{3}PO_{2}(aq)+2CuSO_{4}(aq)+2H_{2}O(l)\rightarrow H_{3}PO_{4}(aq)+2Cu(s)+4H_{2}SO_{4}(aq)$
What inference do you draw about the behaviour of $Ag^{+}$ and $Cu^{+}$ from these reactions?
Answer :
In the first reaction, we can see that $Ag^{+}$ oxidizes the phosphorus from (+1 $\rightarrow$ +5) also in second, we clearly see that $Cu^{+}$ oxidize the phosphorus from (+1 $\rightarrow$ +5).
Both are oxidising agents.
Question 7.18(a) Balance the following redox reactions by ion – electron method
$MnO_{4}^{-}(aq)+ I^{-}(aq)\rightarrow MnO_{2}(s)+ I_{2}(s)$ (In basic medium)
Answer :
reduction half reaction
$MnO_{4}^{-}\rightarrow MnO_{2}$ (+7 to +4)
Add 3 electrons on the LHS side, and after that, to balance charge, add OH ions. And to balance O atom add a water molecule on whichever side it needs
Balance it
$MnO_{4}^{-}+2H_{2}O+3e^{-}\rightarrow MnO_{2} +4OH^{-}$
oxidation half
$I\rightarrow I_{2}$
Balance it
$2I^{-}\rightarrow I_{2}+2e^{-}$
equalising the no. of electrons by multiplying the oxidation half by 3 and the reduction half by 2, and then adding them.
$
6 \mathrm{I}^{-} \rightarrow 3 \mathrm{I}_2+6 e^{-}
$
$
2 \mathrm{MnO}_4^{-}+4 \mathrm{H}_2 \mathrm{O}+6 e^{-} \rightarrow 2 \mathrm{MnO}_2+8 \mathrm{OH}^{-}
$
Overall Reaction:
$
2 \mathrm{MnO}_4^{-}+4 \mathrm{H}_2 \mathrm{O}+6 \mathrm{I}^{-} \rightarrow 2 \mathrm{MnO}_2+3 \mathrm{I}_2+8 \mathrm{OH}^{-}
$
Question 7.18(c) Balance the following redox reactions by ion – electron method
(c) $H_{2}O_{2}(aq)+Fe^{3+}(aq)\rightarrow Fe^{3+}(aq)+H_{2}O(l)$
In acidic medium
Answer :
In acidic medium
oxidation half reaction-
$Fe^{2+}\rightarrow Fe^{3+}+e^{-}$
reduction half reaction-
$H_{2}O_{2}+2H^{+}+2e^{-}\rightarrow 2H_{2}O$
Balancing the reaction
Multiply by 2 on the oxidation half-reaction, then add it with reduction half-reaction
$H_{2}O_{2}+2Fe^{2+}+2H^{+}\rightarrow 2Fe^{3+}+2H_{2}O$
Question 7.18(d) Balance the following redox reactions by ion – electron method
$Cr_{2}O_{7}^{2-}+SO_{2}(g) \rightarrow Cr^{3+}(aq)+SO_{4}^{2-}(aq)$
In acidic medium
Answer :
Half-reaction
Oxidation half $SO_{2}+2H_{2}O\rightarrow SO_{4}^{2-}+4H^{+}+2e^{-}$
Reduction half $Cr_{2}O_{7}^{2-}+14H^{+}+6e^{-}\rightarrow 2Cr^{3+}+3SO^{2-}+H_{2}O$
Balancing them by multiplying the oxidation half by 3 and adding the reaction
$Cr_{2}O_{7}^{2-}+3SO_{2}+2H^{+}\rightarrow 2Cr^{3+}+3SO_{4}^{2-}+H_{2}O$
Question 7.20 What sorts of information can you draw from the following reaction?
$(CN)_{2}(g)+2OH^{-}(aq)\rightarrow CN^{-}(aq) +CNO^{-}(aq)+H_{2}O(l)$
Answer :
Carbon shows different oxidation states according to the compound formula.
Here we can clearly say that Carbon is in its +3 oxidation state.
$(CN)_{2}(+3)\rightarrow CN^{-}(+2)$
$(CN)_{2}(+3)\rightarrow CNO^{-}(+4)$
The oxidation state of carbon is increased(oxidised) and decreased(reduced) as well on the product side. So it is a redox reaction and more specifically, we can say it disproportion redox reaction.
Question 7.21
The $Mn^{3+}$ ion is unstable in solution and undergoes disproportionation to give $Mn^{2+}$ , $MnO_{2}$ and $H^{+}$ ion. Write a balanced ionic equation for the reaction
Answer :
The base equation
$Mn^{3+}\rightarrow Mn^{2+}+MnO_{2}+H^{+}$
write the oxidation half with their oxidation state
$Mn^{3+}(+3)\rightarrow MnO_{2}(+4)$
Balance the charge on $Mn$ by adding 1 $e^{-}$ on the RHS side. To balance charge, add $H^{+}$ ions on the RHS side and then for oxygen balance, add $H_{2}O$ molecule on the LHS side.
$Mn^{3+}+2H_{2}O\rightarrow MnO_{2}+1e^{-}+4H^{+}$
reduction half
$Mn^{3+}(+3)\rightarrow Mn^{2+}(+2)$
balancing the reduction half by adding 1 $e^{-}$ on LHS side
$Mn^{3+}+1e^{-}\rightarrow Mn^{2+}$
Add both balanced reduction half and oxidation half
$2Mn^{3+}+2H_{2}O\rightarrow Mn^{2+}+MnO_{2}+4H^{+}$
Question 7.22 Consider the elements: Cs, Ne, I and F
(a) Identify the element that exhibits only a negative oxidation state.
(b) Identify the element that exhibits only a positive oxidation state
(c) Identify the element that exhibits both positive and negative oxidation states
(d) Identify the element which exhibits neither the negative nor the positive oxidation state.
Answer :
(a) F (because of its highly electronegative in nature)
(b) Cs (highly electropositive)
(c) I (has empty d orbitals)
(d) Ne (inert gas)
Question 7.25 In Ostwald’s process for the manufacture of nitric acid, the first step involves the oxidation of ammonia gas by oxygen gas to give nitric oxide gas and steam. What is the maximum weight of nitric oxide that can be obtained starting only with 10.00 g. of ammonia and 20.00 g of oxygen?
Answer :
we have,
No. of moles of ammonia $(NH_{3})$ = 10/17 = 0.588
No. of moles of oxygen $(O_{2})$ = 20/32= 0.625
Balanced Reaction $4NH_{3}+5O_{2}\rightarrow 4NO + 6H_{2}O$
Here we see that 4 moles of ammonia require 5 moles of oxygen. So
0.588 moles of ammonia = $(5/4)*0.588 = 0.735$ moles of $(O_{2})$ . But we have only 0.625 moles of $(O_{2})$ .
It means oxygen is a limiting reagent and the maximum weight of nitric oxide $(NO)$ can be produced by 0.635 moles of $(O_{2})$
So, 5 moles of $(O_{2})$ produced 4 moles of C.
therefore 0.625 moles of $(O_{2})$ = $(4/5)*0.625 = 0.5$ moles of $(NO)$ .
from Eq. 1
mass of $(NO)$ = number of moles $(NO)$ * molecular weight $(NO)$
= $0.5* 30$
= 15 g
Alternate Method
directly consider the molecular weight
(17*4) g of NH3 required (5*32) g of O to produce (30*4) g of NO
So, 10g of NH3 required (5*32/17*4)*10 = 23.5g of O. But we have only 20g (means O is limiting reagent) whatever the max. NO produce is from 20g of O.
and we know that 5*32g of O produce 30*4 g of NO
So, 20g of O produce = (30*4/5*32)*20 g of NO
= 15g of NO
Question 7.26 Using the standard electrode potentials given in the Table 8.1, predict if the reaction between the following is feasible
(a) $Fe^{3+}(aq)$ and $I^{-}(aq)$
(b) $Ag^{+}(aq)$ and Cu(s)
(c) $Fe^{3+}$ (aq) and Cu(s)
(d) Ag(s) and $Fe^{3+}$ (aq)
(e) $Br_{2}(aq)$ and $Fe^{2+}(aq)$
Answer :
If $E^{0}$ for the overall reaction is positive $\rightarrow$ feasible
negative $\rightarrow$ not feasible
(a) $[Fe^{3+}+ e^{-}\rightarrow Fe^{2+} ]*2: E^{0} = 0.77V$
$2I^{-}\rightarrow I_{2}+2e^{-}: E^{0} = -0.54V$
---------------------------------------------------------------------------------------
$2Fe^{3+}+2I^{-}\rightarrow Fe^{2+}+I_{2}: E^{0} = +0.23V$
(b) $Ag^{+}+e^{-}\rightarrow Ag(s)]*2: E^{0} = +0.80V$
$Cu\rightarrow Cu^{2+}+2e^{-}:E^{0} =-0.34V$
---------------------------------------------------------------------------------------
$2Ag^{+}+Cu\rightarrow 2Ag+Cu^{2+}: E^{0}=+0.46V$
(c) $Fe^{3+}+e^{-}\rightarrow Fe^{2+}]*2 :E^{0}=+0.77V$
$2Br^{-}\rightarrow Br+2e^{- }:E^{0}=-1.09V$
-------------------------------------------------------------------------
$2Fe^{3+}+2Br^{-}\rightarrow 2Fe^{3+}+Br_{2}:E^{0}=-0.32$
(d) $Ag\rightarrow Ag^{+}+e^{-}:E^{0}=-0.80V$
$Fe^{3+}+e^{-}\rightarrow Fe^{2+}:E^{0}==0.77V$
------------------------------------------------------------------------------
$Ag+Fe^{3+}\rightarrow Ag^{+}+Fe^{2+}:E^{0}=-0.03V$
(e) $Br_{2}+2e^{-}\rightarrow 2Br^{-}:E^{0}=+1.09V$
$Fe^{2+}\rightarrow Fe^{3+}+e^{-}]*2:E^{0}=-0.77V$
-------------------------------------------------------------------------------
$Br_{2}+2Fe^{2+}\rightarrow 2Br^{-}+2Fe^{3+}:E^{0}=+0.32V$
Question 7.27(i) Predict the products of electrolysis in each of the following:
(i) An aqueous solution of $AgNO_{3}$ with silver electrodes
Answer :
(i) $AgNO_{3}$ dissociate into $Ag^{+}$ and $NO_{3}^{-}$
Cathode - $Ag^{+}(aq)+e^{-}\rightarrow Ag(s)$ (reduction potential of silver is higher than $H_{2}O$ ) $E^{0} = 0.80V$
Anode - $Ag(s)\rightarrow Ag^{+}(aq)+e^{-}$ ( oxidation potential of silver is higher than water molecule. So silver electrode oxidized ) $E^{0} = -0.83V$
Question 7.27(ii) Predict the products of electrolysis in each of the following:
An aqueous solution $AgNO_{3}$ with platinum electrodes
Answer :
(ii) since platinum $(Pt)$ electrode cannot easily oxidize. So at the anode $H_{2}O$ will oxidize and liberate oxygen and at cathode $Ag$ will be deposited.
At cathode- $Ag^{+}+e^{+}\rightarrow Ag$
At anode- $H_{2}O\rightarrow O_{2}+4H^{+} +4e^{-}$
Question 7.27(iii) Predict the products of electrolysis in each of the following:
(iii) A dilute solution of $H_{2}SO_{4}$ with platinum electrodes
Answer :
Given that sulphuric acid is dilute.
ionize into $H_{2}SO_{4}\rightarrow 2H^{+}+ SO_{4}^{2-}$
At cathode $H^{+}+e^{-}\rightarrow 1/2H_{2}(g)$
At anode, There will be -(liberation of oxygen gas)
$H_{2}O\rightarrow 1/2O_{2}+4H^{+}+4e^{-}$
Question 7.27(iv) Predict the products of electrolysis in each of the following:
An aqueous solution of CuCl2 with platinum electrodes
Answer :
(iv) In aqueous solution $CuCl_{2}$ ionise into $Cu^{2+}$ and $2Cl^{-}$
At the cathode, the copper ion will be deposited because it has a higher reduction potential than the water molecule
At the anode, the lower electrode potential value will be preferred but due to the overpotential of oxygen, the chloride ion gets oxidised at the anode.
Anode- $2Cl^{-}\rightarrow Cl_{2}+2e^{-}$
cathode- $Cu^{2+}+2e^{-}\rightarrow Cu$
Question 7.29 Given the standard electrode potentials
$K^{+}/K = -2.93 V$ $Ag^{+}/Ag = 0.80V$
$Hg^{2+}/Hg= 0.79V$
$Mg^{2+}/Mg = -2.37V$ $Cr^{3+}/Cr = -0.74V$
Arrange these metals in their increasing order of reducing power.
Answer :
A negative electrode potential $(E^{0})$ means the redox couple is a stronger reducing agent. So, as per data, the increasing order of the following is-
$Ag<Hg<Cr<Mg<K$
Question 7.30 Depict the galvanic cell in which the reaction
$Zn(s)+2Ag^{+}\rightarrow Zn^{2+}(aq)+2Ag(s)$
takes place. Further show:
(i) Which of the electrodes is negatively charged?
(ii) the carriers of the current in the cell, and
(iii) individual reaction at each electrode.
Answer :
(i) Zn electrode is negatively charged because it loses electrons (acts as an anode)
(ii) electron flow from a negatively charged electrode to a positively charged electrode (anode to cathode) and the flow of current is just reversed. So current flows through the silver cathode to the zinc anode.
(iii) At Anode- $Zn\rightarrow Zn^{2+}+2e^{-}$
At Cathode $Ag^{+}+e^{-}\rightarrow Ag$
Class 11 Chemistry NCERT Chapter 7: Higher Order Thinking Skills (HOTS) Questions
These redox reactions class 11 question answer help you think deeper and apply what you’ve learned in new ways. They are meant to make you solve problems creatively and understand the chapter better, not just memorize facts.
Question 1. Compounds that should not be used as primary standards in titrimetric analysis are :
A. $\mathrm{Na}_2 \mathrm{Cr}_2 \mathrm{O}_7$
B. Oxalic acid
C. NaOH
D. $\mathrm{FeSO}_4 \cdot 6 \mathrm{H}_2 \mathrm{O}$
E. Sodium tetraborate
Choose the most appropriate answer from the options given below:
1) B and D Only
2) D and E Only
3) C, D and E Only
4) A, C and D Only
Answer:
The primary standard is a highly pure stable compound with a known exact composition that can be accurately weighed and dissolved to creat a solution of known concentration.
Compounds like $\mathrm{NaOH}, \mathrm{FeSO}_4 \cdot 6 \mathrm{H}_2 \mathrm{O}, \mathrm{Na}_2 \mathrm{Cr}_2 \mathrm{O}_7$ are not suitable as primary standards in titrimetric analysis because,
NaOH is hygroscopic and can't be used.
$\mathrm{FeSO}_4 \cdot 6 \mathrm{H}_2 \mathrm{O}$ is unstable and can be easily oxidised.
$\mathrm{Na}_2 \mathrm{Cr}_2 \mathrm{O}_7$ is hygroscopic and can't be used.
Hence, the correct answer is option (4).
Question 2. Based on the data given below:
$\begin{array}{ll}
\mathrm{E}_{\mathrm{Cr}_2 \mathrm{O}_7^{2-} / \mathrm{Cr}^{3+}}^0=1.33 \mathrm{~V} & \mathrm{E}_{\mathrm{Cl}_2 / \mathrm{Cl}^{(-)}}^0=1.36 \mathrm{~V} \\
\mathrm{E}_{\mathrm{MnO}_4^{-} / \mathrm{Mn}^{2+}}^0=1.51 \mathrm{~V} & \mathrm{E}_{\mathrm{Cr}^{3+} / \mathrm{Cr}}^0=-0.74 \mathrm{~V}
\end{array}$
the strongest reducing agent is :
1) $\mathrm{Mn}^{2+}$
2) Cr
3) $\mathrm{MnO}_4^{-}$
4) $\mathrm{Cl}^{-}$
Answer:
For the strongest reducing agent
Reduction potential should be the lowest. Hence, Cr is the strongest reducing agent.
Hence, the correct answer is option (2)
Question 3. Oxidation state of Cr in chromyl chloride is:
1) +5
2) +3
3) +7
4) +6
Answer:
The formula of Chromyl chloride is CrO2Cl2.
Let the oxidation state of Cr be X, then
X+ 2×(–2) + 2×(–1) = 0
X–4–2 = 0
X= +6
Hence, the correct answer is option (4)
Question 4. In which of the following reactions does both oxidation and reduction occur simultaneously?
(1) $\mathrm{Zn}+\mathrm{H}_2 \mathrm{SO}_4 \rightarrow \mathrm{ZnSO}_4+\mathrm{H}_2$
(2) $2 \mathrm{KClO}_3 \rightarrow 2 \mathrm{KCl}+3 \mathrm{O}_2$
(3) $\mathrm{CaCO}_3 \rightarrow \mathrm{CaO}+\mathrm{CO}_2$
(4) $2 \mathrm{HgO} \rightarrow 2 \mathrm{Hg}+\mathrm{O}_2$
Answer:
$\ln 2 \mathrm{KClO}_3 \rightarrow 2 \mathrm{KCl}+3 \mathrm{O}_2:$
Oxidation state of Cl changes from +5 in $\mathrm{KClO}_3$ to -1 in KCl and 0 in $\mathrm{O}_2$. Hence, its a disproportionation redox reaction.
Question 5. In the reaction $2 \mathrm{Na}+\mathrm{H}_2 \rightarrow 2 \mathrm{NaH}$, which statement is correct?
(1) Na is oxidised, $\mathrm{H}_2$ is reduced
(2) Na is reduced, $\mathrm{H}_2$ is oxidised
(3) Both are oxidised
(4) Both are reduced
Answer:
$\mathrm{Na}(0 \rightarrow+1)$ is oxidised
$\mathrm{H}(0 \rightarrow-1)$ is reduced
So, it is a redox reaction with Na as reducing agent and $\mathrm{H}_2$ as oxidising agent.
Question 6: Which of the following oxidation reactions are carried out by both $\mathrm{K}_2 \mathrm{Cr}_2 \mathrm{O}_7$ and $\mathrm{KMnO}_4$ in acidic medium?
A. $\mathrm{I}^- \rightarrow \mathrm{I}_2$
B. $\mathrm{S}^{2-} \rightarrow \mathrm{~S}$
C. $\mathrm{Fe}^{2+} \rightarrow \mathrm{Fe}^{3+}$
D. ${I }^{-} \rightarrow \mathrm{IO}_3^{-}$
E. $\mathrm{S}_2 \mathrm{O}_3{ }^{2-} \rightarrow \mathrm{SO}_4{ }^{2-}$
Choose the correct answer from the options given below :
(1) B, C and D only
(2) A, D and E only
(3) A, B and C only
(4) C, D and E only
Answer:
$\begin{array}{ll}\mathrm{I}^{-} \xrightarrow{\mathrm{H}^{+}} \mathrm{I}_2 & \mathrm{I}^{-} \xrightarrow{\mathrm{OH}^{-}} \mathrm{IO}_3^{-} \\ \mathrm{S}^{-2} \xrightarrow{\mathrm{H}^{+}} \mathrm{S} & \mathrm{S}_2 \mathrm{O}_3^{2-} \xrightarrow{\mathrm{OH^-}} \mathrm{SO}_4^{2-} \\ \mathrm{Fe}^{+2} \longrightarrow \mathrm{Fe}^{+3} \\ \mathrm{~S}_2 \mathrm{O}_3^{2-} \xrightarrow{\mathrm{H}^{+}} \mathrm{S} \downarrow+\mathrm{SO}_4^{2-}\end{array}$
Oxidation reactions are carried out by both $\mathrm{K}_2 \mathrm{Cr}_2 \mathrm{O}_7$ and $\mathrm{KMnO}_4$ in acidic medium by: A, B and C
Hence, the correct answer is option (3).
Question 7: In the reaction
$\mathrm{Zn}+\mathrm{Cu}^{2+} \rightarrow \mathrm{Zn}^{2+}+\mathrm{Cu}$
Which of the following statements is correct?
(1) Zn is reduced
(2) $\mathrm{Cu}^{2+}$ is oxidized
(3) Zn acts as a reducing agent
(4) Cu acts as a reducing agent
Answer:
Oxidation states
Zn: $0 \rightarrow+2 \rightarrow$ oxidation
$\mathrm{Cu}^{2+}:+2 \rightarrow 0 \rightarrow$ reduction
Zn acts as a reducing agent
Hence, the correct answer is option (3).
Question 8: The oxidation number of S in $\mathrm{H}_2 \mathrm{~S}_2 \mathrm{O}_8$ is:
(1) +6
(2) +7
(3) +5
(4) +4
Answer:
Let oxidation number of each $\mathrm{S}=x$
Known values:
$\mathrm{H}=+1(2$ atoms $\rightarrow+2)$
$O=-2(8$ atoms $\rightarrow-16)$
Sum of oxidation numbers = 0
$2(+1)+2 x+8(-2)=0$
$2 x=14 \Rightarrow x=+7$
Hence, the correct answer is option (2).
Approach to Solve Questions of Class 11 Chemistry Chapter 7
Sometimes class 11 chemistry chapter 7 redox reactions question answer seem difficult, but once we understand the basic rules and strategy, it becomes very easy to solve all the questions related to this chapter. We can follow the steps given below to solve questions.
1) First of all, we need to understand the type of question asked as the questions of Redox Reactions can be divided into the following categories-
- Calculation of oxidation number
- Balancing of Redox Reaction
- Identifying the oxidising and reducing agents
- Equivalent weight n-factor
- Calculating the amount of the substance using Redox titration
Practice is key, so improve your accuracy by solving more redox reactions class 11 question answer.
2. Practice assigning oxidation numbers to all elements in a compound or ion. It’s key for identifying what is oxidized and reduced. Also, learn to identify redox changes.
3. Focus on two major methods that are,
- Oxidation number method
- Half-reaction (ion-electron) method
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Practice balancing both acidic and basic medium redox reactions.
4. Attempt all questions by writing steps clearly like identifying oxidation numbers, changes, electrons lost/gained and then balancing the reaction. Some questions may involve mole concepts or equivalent weight in redox reactions, so practice a few numericals to get accuracy.Students can also refer class 11 chemistry chapter 7 redox reactions solutions.