Class 11 Chemistry NCERT Chapter 9: Higher Order Thinking Skills (HOTS) Questions
Some higher-order thinking skills questions with solutions based on the NCERT Exemplar Class 11 Chemistry Solutions Chapter 9 Hydrogen are given below that will help you tackle complex problems. The questions below will help you evaluate your understanding of the concepts.
Question 1: $\mathrm{H}_2 \mathrm{O}_2$ acts as a reducing agent in
Options
1) $2 \mathrm{NaOCl}+\mathrm{H}_2 \mathrm{O}_2 \rightarrow 2 \mathrm{NaCl}+\mathrm{H}_2 \mathrm{O}+\mathrm{O}_2$
2) $\mathrm{Na}_2 \mathrm{~S}+4 \mathrm{H}_2 \mathrm{O}_2 \rightarrow \mathrm{Na}_2 \mathrm{SO}_4+4 \mathrm{H}_2 \mathrm{O}$
3) $2 \mathrm{Fe}^{2+}+2 \mathrm{H}^{+}+\mathrm{H}_2 \mathrm{O}_2 \rightarrow 2 \mathrm{Fe}^{3+}+2 \mathrm{H}_2 \mathrm{O}$
4) $\mathrm{Mn}^{2+}+2 \mathrm{H}_2 \mathrm{O}_2 \rightarrow \mathrm{MnO}_2+2 \mathrm{H}_2 \mathrm{O}$
Answer:
$2 \mathrm{NaO} \stackrel{+1}{\mathrm{Cl}}+\mathrm{H}_2 \mathrm{O}_2 \longrightarrow 2 \mathrm{Na} \stackrel{-1}{\mathrm{Cl}}+\mathrm{H}_2 \mathrm{O}+\mathrm{O}_2$
$\mathrm{H}_2 \mathrm{O}_2$ acts as a reducing agent.
Hence, the answer is option (1).
Question 2: The decreasing order of the hydrogen bonding in the following forms of water is correctly represented by
A.Liquid water
B. Ice
C. Impure water
Choose the correct answer from the options given below:
Options
1) $\mathrm{B}>\mathrm{A}>\mathrm{C}$
2) $\mathrm{A}>\mathrm{B}>\mathrm{C}$
3) $\mathrm{A}=\mathrm{B}>\mathrm{C}$
4) $\mathrm{C}>\mathrm{B}>\mathrm{A}$
Answer:
ice $>$ liquid water $>$ impure water
$\begin{aligned} & \text { ice }>\mathrm{H}_2 \mathrm{O} \text { liq. }>\text { impure } \mathrm{H}_2 \mathrm{O} \\ & \text { Hydrogen bond } \alpha \frac{1}{\text { Temp }}\end{aligned}$
Hence, the correct answer is option (1).
Question 3: Some of the properties of water are described below. Which of them is/are not correct?
(i) Water is known to be a universal solvent.
(ii) Hydrogen bonding is present to a large extent in liquid water.
(iii) There is no hydrogen bonding in the frozen state of water.
(iv) Frozen water is heavier than liquid water.
(1) (i) and (ii)
(2) (ii) and (iv)
(3) (iii) and (iv)
(4) None of the above
Answer:
There is no hydrogen bonding in the frozen state of water, and Frozen water is heavier than liquid water.
Water exhibits different properties in different states due to hydrogen bonding, which exists in a water molecule. Ice is lighter than water due to the fact that there are empty spaces in the tetrahedrons of the hydrogen bonds.
Hence, the answer is option (3).
Question 4: The starting material for the convenient preparation of deuterated hydrogen peroxide $\left(\mathrm{D}_2 \mathrm{O}_2\right)$ in the laboratory is:
(1) BaO
(2) $\mathrm{K}_2 \mathrm{~S}_2 \mathrm{O}_8$
(3) $\mathrm{BaO}_2$
(4) 2-ethylanthraquinone
Answer:
$2 \mathrm{HSO}_4^{-}(\mathrm{aq}) \xrightarrow{\text { Electrolysis }} \mathrm{HO}_3 \mathrm{SOOSO}_3 \mathrm{H}_{(\mathrm{aq})} \xrightarrow{\text { Hydrolysis }} 2 \mathrm{HSO}_4^{-}(\mathrm{aq})+2 \mathrm{H}^{+}$
This method is now used for laboratory preparation $\mathrm{D}_2 \mathrm{O}_2$
$\mathrm{K}_2 \mathrm{~S}_2 \mathrm{O}_8(\mathrm{~s})+2 \mathrm{D}_2 \mathrm{O}(\mathrm{l}) \longrightarrow 2 \mathrm{KDSO}_4(\mathrm{aq})+\mathrm{D}_2 \mathrm{O}_2(\mathrm{l})$
Hence, the answer is the option (2).
Question 5: Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason
Assertion A: Hydrogen is an environment friendly fuel.
Reason R: Atomic number of hydrogen is 1 and it is a very light element.
In the light of the above statements, choose the correct answer from the options given below
(1) A is true but R is false
(2) A is false but R is true
(3) Both and are true and A is the correct explanation of R
(4) Both and are true but is NOT the correct explanation of A
Answer:
No pollution occurs by combustion of hydrogen and very low density of hydrogen.
Hence, the answer is the option (4).
Question 6: $\mathrm{O}-\mathrm{O}$ bond length in $\mathrm{H}_2 \mathrm{O}_2$ is $\underline{\mathrm{X}}$ than the $\mathrm{O}-\mathrm{O}$ bond length in $\mathrm{F}_2 \mathrm{O}_2$. The $\mathrm{O}-\mathrm{H}$ bond length in $\mathrm{H}_2 \mathrm{O}_2$ is $\underline{Y}$ than that of the $\mathrm{O}-\mathrm{F}$ bond in $\mathrm{F}_2 \mathrm{O}_2$.
Choose the correct option for $X$ and $Y$ from those given below
(1) X-shorter, Y - longer
(2) X-shorter, Y-shorter
(3) X-longer, Y-shorter
(4) X-longer, Y-longer
Answer:
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$\rightarrow(\mathrm{O}-\mathrm{O}) \mathrm{BL}$ in $\mathrm{H}_2 \mathrm{O}_2$ in longer then $(\mathrm{O}-\mathrm{O}) \mathrm{BL}$ in $\mathrm{O}_2 \mathrm{~F}_2$
$\rightarrow(\mathrm{O}-\mathrm{H}) \mathrm{BL}$ in $\mathrm{H}_2 \mathrm{O}_2$ in shorter than $(\mathrm{O}-\mathrm{F}) \mathrm{BL}$ in $\mathrm{O}_2 \mathrm{~F}_2$
Hence, the answer is the option (3).
Question 7: Given below are two statements :
Statement I : $\mathrm{H}_2 \mathrm{O}_2$ is used in the synthesis of Cephalosporin
Statement II : $\mathrm{H}_2 \mathrm{O}_2$ is used for the restoration of aerobic conditions to sewage wastes.
In the light of the above statements, choose the most appropriate answer from the options given below:
(1) Both Statement I and Statement II are incorrect
(2) Statement I is incorrect but Statement II is correct
(3) Statement I is correct but Statement II is incorrect
(4) Both Statement I and Statement II are correct
Answer:
$\mathrm{H}_2 \mathrm{O}_2$ is used in the synthesis of hydroquinone, tartaric acid and certain food products and pharmaceuticals (cephalosporin). Nowadays it is also used in environmental (green) chemistry for example in pollution control treatment of domestic and industrial effluents, oxidation of cyanides restoration of aerobic conditions to sewage waste. Hence both statements are correct.
Hence, the answer is the option (4).
Approaches to Solve Questions of Chapter 9 Hydrogen
To solve class 11 chemistry Chapter 9 Hydrogen questions, it is important to follow a systematic approach. Given below the approaches to solve these questions effectively.
1. While solving questions from Hydrogen students are guided to first understand the basic concepts like Position of Hydrogen, Occurrence, Preparation of Dihydrogen, Properties of Dihydrogen, Electron Configuration.
2. It is very important to understand the position of hydrogen because many reasoning questions are asked on hydrogen dual resemblance with alkali metals and halogens. It is very important to understand the position of hydrogen because many reasoning questions are asked on hydrogen dual resemblance with alkali metals and halogens. Students can also refer to NCERT Class 11 Chapter 9 Hydrogen notes to understand these concepts in detail.
3. Questions from this topic are frequently asked in exams. Learn properties of protium, deuterium, tritium. Approach questions on isotopes by focusing on occurrence, stability, and uses.
4. Learn about the preparation methods from water, metals, and industrial processes, and then write the balanced equations with proper conditions like temperature or catalyst. For its properties, focus on physical features in short and emphasise chemical reactivity by writing reactions as these are commonly asked in exams.
5. Be thorough with the preparation, properties, and uses of compounds like water, heavy water, and hydrogen peroxide. Questions may also involve their structure, bonding, and behaviour in reactions. Understand the concept of hydrogen bonding in water and other compounds. Many reasoning questions test its role in anomalous properties of water, such as high boiling point and density anomali
6. Practice questions from NCERT Exemplar solutions Chapter 9 Hydrogen Class 11 Chemistry, as these questions are asked directly in boards and other competitive exams. For revision students can follow Class 11 Hydrogen Chemistry Notes. While solving questions, students must take care of a few basic points like, converting the units where required, and significant figures must be thoroughly checked.