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Free NCERT Class 12 Chemistry Chapter 11 Notes Alcohols, Phenols and Ethers - Download PDF

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Free NCERT Class 12 Chemistry Chapter 11 Notes Alcohols, Phenols and Ethers - Download PDF

Edited By Sumit Saini | Updated on Apr 09, 2024 02:46 PM IST

The NCERT Class 12 Chemistry chapter 11 notes are very important for the exam. Students will study about the preparation, characteristics, and reactivity of alcohols, phenols, and ethers in this chapter. This chapter addresses some of the most fundamental topics in organic chemistry, as well as their industrial applications. Integrating ch 11 Chemistry Class 12 notes into one's study routine will help students in better comprehension of alcohols, phenols, and ethers, enhancing problem-solving skills and analytical abilities. CBSE Class 12 Chemistry Ch 11 notes provide a structured overview of the syllabus, guiding students through essential topics and highlighting crucial points for effective revision.

Comprehensive reading of alcohols, phenols and ethers notes class 12 is essential for gaining a thorough understanding of this segment of organic chemistry. cbse class 12 chemistry ch 11 notes provide a brief synopsis of the chapter for quick preparation of CBSE board exams and school-based annual examinations.

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NCERT Class 12 Chemistry Chapter 11 Notes

NCERT Class 12 Chemistry Chapter 11 Notes: Topic 1

Classification of Alcohols and Phenols

  • Alcohols and phenols are classed as monohydric, dihydric, trihydric, or polyhydric depending on how many hydroxyl groups they have in their molecules: one, two, three, or many, respectively

  • Alcohols with the OH group connected to a primary, secondary, or tertiary carbon atom are known as primary (1°), secondary (2°), and tertiary (3°) alcohols.

  • Allylic alcohol is made up of an -OH group attached to an sp3 hybridized carbon next to a carbon carbon double bond, whereas benzylic alcohol is made up of an -OH group attached to an sp3 hybridized carbon close to an aromatic ring. Alcohols having -OH group bonded to carbon-carbon double bond is called vinylic alcohol

NCERT Class 12 Chemistry Chapter 11 Notes: Topic 2

Structure of Alcohols and Phenols

Alcohols have sp3 hybridized oxygen atoms and hybrid atomic orbitals in a tetrahedral configuration. The R group determines the value of the LROH bond angle. Due to lone pair repulsion, this angle for of methyl alcohol is (C – O – H) 108.9°.The -OH group in phenols is connected to sp2 hybridized carbon, giving the C – O bond a partial double bond nature.

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NCERT Class 12 Chemistry Chapter 11 Notes: Topic 3

Preparation of Alcohols

  • From alkenes

This reaction is in accordance with Markonikov's rule, through acid catalyzed hydration.

CH3CH=CH2 + H2O → CH3-CH(OH) - CH3

  • By hydroboration-oxidation

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  • By reduction of aldehydes and ketones

RCHO + H2 → R CH2OH

RCOR \overset{NaBH4}{\rightarrow}R-CH(OH)-R

  • By reduction of carboxylic acids

RCOOH\overset{LiAlH_4, H_2O}{\rightarrow} ROH

  • From Grignard reagents

HCHO + RMgX \overset{H_2O}{\rightarrow}RCH_2OH + Mg(OH)X

RCHO + RMgX \overset{H_2O}{\rightarrow} R-CH(R)OH + Mg(OH)X

RCOR + RMgX \overset{H_2O}{\rightarrow}R-C(R)(R)OH + Mg(OH)X

NCERT Class 12 Chemistry Chapter 11 Notes: Topic 4

Preparation of Phenols

  • From haloarenes

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  • From benzenesulfonicacid

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  • From diazonium salts

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  • From cumenes

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NCERT Class 12 Chemistry Chapter 11 Notes: Topic 5

Physical Properties of Alcohols and Phenols

Lower alcohols are colourless liquids, C5–C11 alcohols are oily liquids, and C12 and higher alcohols are waxy solids. Alcohols are miscible with water because their hydroxyl groups can form H-bonds with water. With increasing molecular mass, solubility decreases. Because polar molecules have intermolecular hydrogen bonding, the boiling points of alkanes are greater than expected.

These are colourless liquids or crystalline solids that turn coloured over time due to gradual oxidation in the presence of air. Carboxylic acid is another name for phenol. Phenols establish intermolecular H-bonds with other phenol molecules and with water due to the presence of a polar -OH bond.

NCERT Class 12 Chemistry Chapter 11 Notes: Topic 6

Chemical Reactions of Alcohols and Phenols

  • Acidity of alcohols and phenols

Reaction with metals

2 R-OH + 2Na \overset{yields}{\rightarrow}2 R-O-Na+H_2

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Acidity of alcohols

  • The polar nature of the OH bond causes the acidity of alcohols.

  • Order of acidity

Primary > Secondary Tertiary

  • Alcohols are weaker acids than water

Acidity of phenols

Because the phenoxide ion is stabilized through resonance, phenol is more acidic than alcohols. The presence of an electron withdrawing group raises phenol's acidity by stabilizing the phenoxide ion, whereas the presence of an electron releasing group lowers phenol's acidity by destabilizing the phenoxide ion.

  • Esterification

Ar/R-OH + R-COOH \overset{H^+}{\rightarrow} Ar/ROCOR + H_2OAr/R-OH + (RCO,)2O + H+↔ Ar/ROCOR, + RCOOH

R/ArOH + R,COCl Pyridine→ R/ArOCOR, + HCl

  • Reaction with hydrogen halides

ROH + HX yields→ RX + H2O

  • Dehydration

Alcohols H+, Heat→ Alkene + H2O

Order of reaction

Tertiary > Secondary > Primary

  • Oxidation

Alcohol Acidified KMnO4→ Carboxylic acid

RCH2OH Oxidation→ RCHO yields→ RCOOH

  • Reactions of phenol

  • Halogenation

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  • Nitration

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  • Reimer-Tiemann reaction

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  • Kolbe’s reaction

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  • Reaction with zinc dust

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  • Oxidation

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NCERT Class 12 Chemistry Chapter 11 Notes: Topic 7

Some Commercially Important Alcohols

  • Methanol (CH3OH)

  • Wood-spirit is another name for it. It is a clear liquid with no discernible colour. It reaches a temperature of 337 degrees Fahrenheit when it boils. It is extremely poisonous. Even little doses can cause blindness, and excessive doses can even result in death

  • Preparation

CO + 2H2 ZnO-Cr2O3,200-300 atm,573-673 K→ CH3OH

  • Uses: Paints, varnishes, and other products use it as a solvent.It can be used to make formaldehyde.

  • Ethanol (C2H5OH)

  • It is known as denatured spirit when combined with CuSO4 and pyridine.It is a colourless liquid having boiling point 351 K

  • Preparation

C12H22O11 + H2O Invertase→ C6H12O6 Glucose+ C6H12O6 Fructose

C6H12O6 Zymase→ 2 C2H5OH + 2 CO2

  • Uses: It is a good solvent, Sterilization of surgical tools in laboratories and hospitals.

NCERT Class 12 Chemistry Chapter 11 Notes: Topic 8

Preparation of Ether

  • By dehydration of alcohols

CH3CH2OH+ H2SO4,443 K→ CH2= CH2

CH3CH2OH + H2SO4,413 K→ C2H5OC2H5

  • Williamson synthesis

R-X + R-O-Na yields→ R-O-R + NaX

NCERT Class 12 Chemistry Chapter 11 Notes: Topic 9

Physical Properties of Ethers

Since ethers' C-O bonds are polar, they have a net dipole moment. Their boiling points are equivalent to alkanes with similar molecular weights, although they are lower than alcohols. It's because ethers don't have H-bonding. Ether miscibility with water is similar to that of alcohols of same molar mass. It's because ethers, like alcohols, can make H-bonds with water.

NCERT Class 12 Chemistry Chapter 11 Notes: Topic 10

Chemical Properties of Ethers

  • Cleavage of C-O bonds

R-O-R + HX yields→ RX + R-OH

R-OH + HX yields R-X + H2O

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R-O-R + HX yields→ R-X + R-OH

  • Electrophilic substitution reactions

  • Halogenation

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  • Friedel craft’s reaction

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  • Nitration

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Significance of NCERT Class 12 Chemistry Chapter 11 Notes

Alcohols, Phenols and Ethers class 12 notes provides significant insights for board exams, and competitive exams like JEE and NEET. Class 12 chemistry chapter 10 notes can help you grasp the fundamental principles. This chapter is also useful for entrance exams and competitive exams like VITEEE, BITSAT, JEE Main Core, NEET, etc. As a result, knowledge of that chapter becomes much more important. Class 12 Chemistry chapter 11 notes make it easy to go over the entire chapter 11 in a few minutes. One of the best exam-day strategies given by lecturers is to take Alcohols, Phenols and Ethers Class 12 notes. Students can study offline by downloading chemistry class 12 chapter 11 notes pdf .

NCERT Class 12 Notes Chapter-Wise

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Subject Wise NCERT Solutions

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Frequently Asked Question (FAQs)

1. 1. What are the main reactions of alcohols covered in the Alcohols, Phenols and Ethers Class 12 notes?

Ans- Acidity of alcohols, esterification, oxidation, dehydration, etc are discussed in Class 12 Chemistry chapter 11 notes.

2. 2. What are the main topics covered in Notes for Class 12 Chemistry chapter 11.

Ans-. Classification of alochols and phenols, preparation of alcohols,phenols and ethers , physical and chemical properties of alcohols , phenols and ethers etc are covered in NCERT notes for Class 12 Chemistry chapter 11.

3. 3.What is the difference between alcohols and phenols according to Alcohols, phenols and ethers Class 12 notes?

Ans- One or more hydroxyl groups are connected to a saturated carbon atom in alcohols. A hydroxyl group is linked to an aromatic hydrocarbon system in phenols.

4. 4. What is alcohol, phenol, and ether as given by Class 12 Alcohols, phenols and ethers notes?

Ans- In alcohols a hydroxyl group is attached to a saturated carbon atom in alcohol, which is an organic molecule. Phenol is an organic compound formed when a hydrogen atom in a benzene molecule is replaced by a -OH group. Ether is an organic molecule composed of two aryl or alkyl groups joined by an oxygen atom. This is mentioned in Class12 Alcohols , phenols and ethers notes.

5. 5. What are the applications of ethanol, phenol, and ether as per CBSE Class 12 Chemistry chapter 11 notes?

Ans- Fats, oils, waxes, resins, dyers, gums, and other materials employ ethers as a solvent. Alcohol is a key component in alcoholic beverages. They're also used in the ink, medicine, and ink industries etc. Antiseptic properties of phenols are widely used in pharmaceuticals. Alcohols, phenols, and ether are important ingredients in detergents, antiseptics, and scents. More details are available in Alcohols, phenols and ethers Class 12 pdf download.

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A block of mass 0.50 kg is moving with a speed of 2.00 ms-1 on a smooth surface. It strikes another mass of 1.00 kg and then they move together as a single body. The energy loss during the collision is

Option 1)

0.34\; J

Option 2)

0.16\; J

Option 3)

1.00\; J

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0.67\; J

A person trying to lose weight by burning fat lifts a mass of 10 kg upto a height of 1 m 1000 times.  Assume that the potential energy lost each time he lowers the mass is dissipated.  How much fat will he use up considering the work done only when the weight is lifted up ?  Fat supplies 3.8×107 J of energy per kg which is converted to mechanical energy with a 20% efficiency rate.  Take g = 9.8 ms−2 :

Option 1)

2.45×10−3 kg

Option 2)

 6.45×10−3 kg

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 9.89×10−3 kg

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12.89×10−3 kg

 

An athlete in the olympic games covers a distance of 100 m in 10 s. His kinetic energy can be estimated to be in the range

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2,000 \; J - 5,000\; J

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200 \, \, J - 500 \, \, J

Option 3)

2\times 10^{5}J-3\times 10^{5}J

Option 4)

20,000 \, \, J - 50,000 \, \, J

A particle is projected at 600   to the horizontal with a kinetic energy K. The kinetic energy at the highest point

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K/2\,

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\; K\;

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zero\;

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K/4

In the reaction,

2Al_{(s)}+6HCL_{(aq)}\rightarrow 2Al^{3+}\, _{(aq)}+6Cl^{-}\, _{(aq)}+3H_{2(g)}

Option 1)

11.2\, L\, H_{2(g)}  at STP  is produced for every mole HCL_{(aq)}  consumed

Option 2)

6L\, HCl_{(aq)}  is consumed for ever 3L\, H_{2(g)}      produced

Option 3)

33.6 L\, H_{2(g)} is produced regardless of temperature and pressure for every mole Al that reacts

Option 4)

67.2\, L\, H_{2(g)} at STP is produced for every mole Al that reacts .

How many moles of magnesium phosphate, Mg_{3}(PO_{4})_{2} will contain 0.25 mole of oxygen atoms?

Option 1)

0.02

Option 2)

3.125 × 10-2

Option 3)

1.25 × 10-2

Option 4)

2.5 × 10-2

If we consider that 1/6, in place of 1/12, mass of carbon atom is taken to be the relative atomic mass unit, the mass of one mole of a substance will

Option 1)

decrease twice

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increase two fold

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remain unchanged

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be a function of the molecular mass of the substance.

With increase of temperature, which of these changes?

Option 1)

Molality

Option 2)

Weight fraction of solute

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Fraction of solute present in water

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Mole fraction.

Number of atoms in 558.5 gram Fe (at. wt.of Fe = 55.85 g mol-1) is

Option 1)

twice that in 60 g carbon

Option 2)

6.023 × 1022

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half that in 8 g He

Option 4)

558.5 × 6.023 × 1023

A pulley of radius 2 m is rotated about its axis by a force F = (20t - 5t2) newton (where t is measured in seconds) applied tangentially. If the moment of inertia of the pulley about its axis of rotation is 10 kg m2 , the number of rotations made by the pulley before its direction of motion if reversed, is

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less than 3

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more than 3 but less than 6

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more than 6 but less than 9

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more than 9

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In a career as a vlogger, one generally works for himself or herself. However, once an individual has gained viewership there are several brands and companies that approach them for paid collaboration. It is one of those fields where an individual can earn well while following his or her passion. 

Ever since internet costs got reduced the viewership for these types of content has increased on a large scale. Therefore, a career as a vlogger has a lot to offer. If you want to know more about the Vlogger eligibility, roles and responsibilities then continue reading the article. 

3 Jobs Available
Publisher

For publishing books, newspapers, magazines and digital material, editorial and commercial strategies are set by publishers. Individuals in publishing career paths make choices about the markets their businesses will reach and the type of content that their audience will be served. Individuals in book publisher careers collaborate with editorial staff, designers, authors, and freelance contributors who develop and manage the creation of content.

3 Jobs Available
Journalist

Careers in journalism are filled with excitement as well as responsibilities. One cannot afford to miss out on the details. As it is the small details that provide insights into a story. Depending on those insights a journalist goes about writing a news article. A journalism career can be stressful at times but if you are someone who is passionate about it then it is the right choice for you. If you want to know more about the media field and journalist career then continue reading this article.

3 Jobs Available
Editor

Individuals in the editor career path is an unsung hero of the news industry who polishes the language of the news stories provided by stringers, reporters, copywriters and content writers and also news agencies. Individuals who opt for a career as an editor make it more persuasive, concise and clear for readers. In this article, we will discuss the details of the editor's career path such as how to become an editor in India, editor salary in India and editor skills and qualities.

3 Jobs Available
Reporter

Individuals who opt for a career as a reporter may often be at work on national holidays and festivities. He or she pitches various story ideas and covers news stories in risky situations. Students can pursue a BMC (Bachelor of Mass Communication), B.M.M. (Bachelor of Mass Media), or MAJMC (MA in Journalism and Mass Communication) to become a reporter. While we sit at home reporters travel to locations to collect information that carries a news value.  

2 Jobs Available
Corporate Executive

Are you searching for a Corporate Executive job description? A Corporate Executive role comes with administrative duties. He or she provides support to the leadership of the organisation. A Corporate Executive fulfils the business purpose and ensures its financial stability. In this article, we are going to discuss how to become corporate executive.

2 Jobs Available
Multimedia Specialist

A multimedia specialist is a media professional who creates, audio, videos, graphic image files, computer animations for multimedia applications. He or she is responsible for planning, producing, and maintaining websites and applications. 

2 Jobs Available
Welding Engineer

Welding Engineer Job Description: A Welding Engineer work involves managing welding projects and supervising welding teams. He or she is responsible for reviewing welding procedures, processes and documentation. A career as Welding Engineer involves conducting failure analyses and causes on welding issues. 

5 Jobs Available
QA Manager
4 Jobs Available
Quality Controller

A quality controller plays a crucial role in an organisation. He or she is responsible for performing quality checks on manufactured products. He or she identifies the defects in a product and rejects the product. 

A quality controller records detailed information about products with defects and sends it to the supervisor or plant manager to take necessary actions to improve the production process.

3 Jobs Available
Production Manager
3 Jobs Available
Product Manager

A Product Manager is a professional responsible for product planning and marketing. He or she manages the product throughout the Product Life Cycle, gathering and prioritising the product. A product manager job description includes defining the product vision and working closely with team members of other departments to deliver winning products.  

3 Jobs Available
QA Lead

A QA Lead is in charge of the QA Team. The role of QA Lead comes with the responsibility of assessing services and products in order to determine that he or she meets the quality standards. He or she develops, implements and manages test plans. 

2 Jobs Available
Structural Engineer

A Structural Engineer designs buildings, bridges, and other related structures. He or she analyzes the structures and makes sure the structures are strong enough to be used by the people. A career as a Structural Engineer requires working in the construction process. It comes under the civil engineering discipline. A Structure Engineer creates structural models with the help of computer-aided design software. 

2 Jobs Available
Process Development Engineer

The Process Development Engineers design, implement, manufacture, mine, and other production systems using technical knowledge and expertise in the industry. They use computer modeling software to test technologies and machinery. An individual who is opting career as Process Development Engineer is responsible for developing cost-effective and efficient processes. They also monitor the production process and ensure it functions smoothly and efficiently.

2 Jobs Available
QA Manager
4 Jobs Available
AWS Solution Architect

An AWS Solution Architect is someone who specializes in developing and implementing cloud computing systems. He or she has a good understanding of the various aspects of cloud computing and can confidently deploy and manage their systems. He or she troubleshoots the issues and evaluates the risk from the third party. 

4 Jobs Available
Azure Administrator

An Azure Administrator is a professional responsible for implementing, monitoring, and maintaining Azure Solutions. He or she manages cloud infrastructure service instances and various cloud servers as well as sets up public and private cloud systems. 

4 Jobs Available
Computer Programmer

Careers in computer programming primarily refer to the systematic act of writing code and moreover include wider computer science areas. The word 'programmer' or 'coder' has entered into practice with the growing number of newly self-taught tech enthusiasts. Computer programming careers involve the use of designs created by software developers and engineers and transforming them into commands that can be implemented by computers. These commands result in regular usage of social media sites, word-processing applications and browsers.

3 Jobs Available
Product Manager

A Product Manager is a professional responsible for product planning and marketing. He or she manages the product throughout the Product Life Cycle, gathering and prioritising the product. A product manager job description includes defining the product vision and working closely with team members of other departments to deliver winning products.  

3 Jobs Available
Information Security Manager

Individuals in the information security manager career path involves in overseeing and controlling all aspects of computer security. The IT security manager job description includes planning and carrying out security measures to protect the business data and information from corruption, theft, unauthorised access, and deliberate attack 

3 Jobs Available
ITSM Manager
3 Jobs Available
Automation Test Engineer

An Automation Test Engineer job involves executing automated test scripts. He or she identifies the project’s problems and troubleshoots them. The role involves documenting the defect using management tools. He or she works with the application team in order to resolve any issues arising during the testing process. 

2 Jobs Available
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