NCERT solutions for Class 12 Chemistry Chapter 7 Alcohols, Phenols and Ethers

Question 7.1 (2) Classify the following as primary, secondary and tertiary alcohols:

Answer :

To classify we look at the OH bonded carbon.

Here, only 1 carbon is attached to it, hence it is primary alcohol.

Question 7.1 (3) Classify the following as primary, secondary and tertiary alcohols:

$CH_3 -CH_2- CH_2 -OH$

Answer :

To classify we look at the OH bonded carbon.

Here, only 1 carbon is attached to it, hence it is primary alcohol.

Question 7.1 (4) Classify the following as primary, secondary and tertiary alcohols:

Answer :

To classify we look at the OH bonded carbon.

Here, 2 carbons are attached to it, hence it is secondary alcohol.

Question 7.1 (5) Classify the following as primary, secondary and tertiary alcohols:

Answer :

To classify we look at the OH bonded carbon.

Here, 2 carbons are attached to it, hence it is secondary alcohol.

Question 7.1 (6) Classify the following as primary, secondary and tertiary alcohols :

Answer:

To classify we look at the OH bonded carbon.

Here, 3 carbons are attached to it, hence it is tertiary alcohol.

Question 7.2 Identify allylic alcohols in the above examples.

Answer :

The alcohols (ii) and (vi) are allylic alcohols. Because -C=C-C-OH is the skeleton of allylic alcohol.

Question 7.3 (1) Name the following compounds according to IUPAC system.

Answer :

3-Chloromethyl-2-isopropylpentan-1-ol

Question 7.3 (2) Name the following compounds according to IUPAC system.

Answer :

2, 5-Dimethylhexane-1, 3-diol

Question 7.3 (3) Name the following compounds according to IUPAC system.

Answer :

3-Bromocyclohexanol

Question 7.3 (4) Name the following compounds according to IUPAC system.

Answer :

Hex-1-en-3-ol

Question 7.3 (5) Name the following compounds according to IUPAC system.

Answer :

2-Bromo-3-methylbut-2-en-1-ol

Question 7.4 (1) Show how are the following alcohols prepared by the reaction of a suitable Grignard reagent on methanal ?

Answer :

The reaction of a suitable Grignard reagent on the methanal is mentioned below:

Question 7.4 (2) Show how are the following alcohols prepared by the reaction of a suitable
Grignard reagent on methanal ?

Answer :

Question 7.5 (1) Write structures of the products of the following reactions:

Answer :

Question 7.5 (2) Write structures of the products of the following reactions:

Answer :

The product of the given reaction is-

Question 7.5 (3) Write structures of the products of the following reactions:

Answer :

Product of the given reaction is

Question 7.6 (1) Give structures of the products you would expect when each of the following alcohol reacts with

(a) $HCL- ZnCl_2$ with Butan-1-ol

Answer :

Primary alcohols do no react with Lucas’ reagent.

Hence no reaction.

Question 7.6 (2) Give structures of the products you would expect when each of the following alcohol reacts with $HCl - ZnCl_2$ with 2-Methylbutan-2-ol

Answer :

Reaction of $HCl - ZnCl_2$ with 2-Methylbutan-2-ol

Question7.6 (3) Give structures of the products you would expect when each of the following alcohol reacts with HBr with Butan-1-ol

Answer :

Reaction of HBr with Butan-1-ol

Question 7.6 (4) Give structures of the products you would expect when each of the following alcohol reacts with HBr with 2-Methylbutan-2-ol

Answer :

Reaction of HBr with 2-Methylbutan-2-ol

Question 7.6 (5) Give structures of the products you would expect when each of the following alcohol reacts with $SOCl_2$ with Butan-1-ol

Answer :

Reaction of $SOCl_2$ with Butan-1-ol

Question 7.6 (6) Give structures of the products you would expect when each of the following alcohol reacts with $SoCl_2$ with 2-Methylbutan-2-ol

Answer :

Reaction of $SoCl_2$ with 2-Methylbutan-2-ol

Question 7.7(1) Predict the major product of acid catalysed dehydration of 1-methylcyclohexanol

Answer :

Dehydration of 1-methylcyclohexanol

1-Methylcyclohexene is the major product.

Question 7.7 (2) Predict the major product of acid catalysed dehydration of butan-1-ol

Answer :

Dehydration of butan-1-ol

But-2-ene is the major product.

Question 7.8 Ortho and para nitrophenols are more acidic than phenol. Draw the resonance structures of the corresponding phenoxide ions.

Answer :

Resonance structure of ortho-nitrophenol

Resonance structure of para-nitrophenol

Question 7.9 (1) Write the equations involved in the following reactions: Reimer - Tiemann reaction

Answer :

Reimer - Tiemann reaction

Question 7.9 (2) Write the equations involved in the following reactions: Kolbe’s reaction

Answer :

Kolbe’s reaction

Question 7.10 Write the reactions of Williamson synthesis of 2-ethoxy-3-methylpentane starting from ethanol and 3-methylpentan-2-ol.

Answer :

1.Reaction of ethanol with hydrogen bromide.

2. Reaction of 3-methylpentan-2-ol with sodium

3. Reaction of product formed in 1st and reaction with the product formed in the 2nd reaction.

Question 7.11 Which of the following is an appropriate set of reactants for the preparation of 1-methoxy-4-nitrobenzene and why?

Answer :

(ii) is appropriate because $CH_3Br$ is nucleophile whereas $CH_3ONa$ is also a strong base. So elimination will be dominating in (i).

Question 7.12 (1) Predict the products of the following reactions:

$CH_3 -CH_2 -CH_2 -O - CH_3 +HBr$

Answer :

Reaction is

Question 7.12 (2) Predict the products of the following reactions:

Answer :

The reaction between ethoxybenzene and HBr is

Question 7.12 (3) Predict the products of the following reactions:

Answer :

Reaction between ethoxybenzene and $Conc. \:H_{2}SO_{4} \:+\:conc. HNO_{3}$

Question 7.12 (4) Predict the products of the following reactions:

Answer :

Reaction between ter - butyl ethyl ether and HI

Question 7.1 (2) Write IUPAC names of the following compounds:

Answer :

IUPAC name of the given compound is 5-Ethylheptane-2,4-diol

Question 7.1 (3) Write IUPAC names of the following compounds:

Answer :

IUPAC name of the given compound is Butane-2,3-diol

Question 7.1 (4) Write IUPAC names of the following compounds:

Answer :

IUPAC name of the given compound is Propane-1,2,3-triol

Question 7.1 (5) Write IUPAC names of the following compounds:

Answer :

IUPAC name of the given compound is 2-Methylphenol

Question 7.1 (6) Write IUPAC names of the following compounds:

Answer :

IUPAC name of the given compound is 4-Methylphenol

Note : Also called p-cresol

Question 7.1 (7) Write IUPAC names of the following compounds:

Answer :

IUPAC name of the given compound is 2,5-Dimethylphenol

Question 7.1 (8) Write IUPAC names of the following compounds:

Answer :

IUPAC name of the given compound is 2,6-Dimethylphenol

Question 7.1 (9) Write IUPAC names of the following compounds:

Answer :

IUPAC name of the given compound is 1-Methoxy-2-methylpropane

Question 7.1 (10) Write IUPAC names of the following compounds:

Answer :

IUPAC name of the given compound is Ethoxybenzene

Question 7.1 (11) Write IUPAC names of the following compounds:

Answer :

IUPAC name of the given compound is 1-Phenoxyheptane

Question 7.1 (12) Write IUPAC names of the following compounds:

Answer :

IUPAC name of the given compound is 2-Ethoxybutane

Question 7.2 Write structures of the compounds whose IUPAC names are as follows:
(i) 2-Methylbutan-2-ol

Answer :

Structure of 2-Methylbutan-2-ol

Question 7.2 Write structures of the compounds whose IUPAC names are as follows: (ii) 1-Phenylpropan-2-ol

Answer :

Structure of 1-Phenylpropan-2-ol

Question 7.2(iii) Write structures of the compounds whose IUPAC names are as follows: (iii) 3,5-Dimethylhexane –1, 3, 5-triol

Answer :

structure of 3,5-Dimethylhexane –1, 3, 5-triol

Question 7.2(iv) Write structures of the compounds whose IUPAC names are as follows: (iv) 2,3 – Diethylphenol

Answer :

structure of 2,3 – Diethylphenol

Question 7.2(v) Write structures of the compounds whose IUPAC names are as follows:
(v) 1 – Ethoxypropane

Answer :

structure of 1 – Ethoxypropane

Question 7.2(vi) Write structures of the compounds whose IUPAC names are as follows:
(vi) 2-Ethoxy-3-methylpentane

Answer :

structure of 2-Ethoxy-3-methylpentane

Question 7.2(vii) Write structures of the compounds whose IUPAC names are as follows:
(vii) Cyclohexylmethanol

Answer :

Structure of Cyclohexylmethanol

Question 7.2(viii) Write structures of the compounds whose IUPAC names are as follows:
(viii) 3-Cyclohexylpentan-3-ol

Answer :

The structure of 3-Cyclohexylpentan-3-ol is as follows:

Question 7.2(ix) Write structures of the compounds whose IUPAC names are as follows:
(ix) Cyclopent-3-en-1-ol

Answer :

structure of Cyclopent-3-en-1-ol

Question 7.2(x) Write structures of the compounds whose IUPAC names are as follows:
(x) 4-Chloro-3-ethylbutan-1-ol.

Answer :

structure of 4-Chloro-3-ethylbutan-1-ol

Question 7.3 (i) Draw the structures of all isomeric alcohols of molecular formula $C_5 H_{12}O$
and give their IUPAC names.

Answer :

The structures of all isomeric alcohols of C ₅ H ₁₂ O are given below:

	Pentan-1-ol
	Pentan-2-ol
	Pentan-3-ol
	3-Methylbutan-1-ol
	2,2-Dimethylpropan-1-ol
	3-Methylbutan-2-ol
	2-Methylbutan-2-ol

Question 7.3 (ii) Classify the isomers of alcohols in question 11.3 (i) as primary, secondary and tertiary alcohols.

Answer :

Primary Alcohol: Pentan-1-ol; 2-Methylbutan-1-ol; 3-Methylbutan-1-ol; 2,2-Dimethylpropan-1-ol

Secondary Alcohol: Pentan-2-ol; 3-Methylbutan-2-ol; Pentan-3-ol

Tertiary Alcohol: 2-Methylbutan-2-ol

Question 7.4 Explain why propanol has higher boiling point than that of the hydrocarbon, butane?

Answer :

Propanol forms intermolecular H-bonds because of the presence of -OH group while butane cannot. To break these bonds, extra energy will be required. This causes a higher boiling point for propanol as compared to butane.

Question 7.5 Alcohols are comparatively more soluble in water than hydrocarbons of comparable molecular masses. Explain this fact.

Answer :

Alcohols form hydrogen bonds with water due to the presence of –OH group whereas hydrocarbons cannot. Due to this inter molecular hydrogen bonding, alcohols are more soluble in water.

Question 7.6 What is meant by hydroboration-oxidation reaction? Illustrate it with an example.

Answer :

Hydroboration-oxidation reaction also called HBO reaction is the addition of borane followed by oxidation to produce alcohol.

Eg: Hydroboration-oxidation reaction of propene. In this reaction, propene reacts with diborane (BH₃)₂ to form trialkyl borane. This addition product is oxidized by hydrogen peroxide in the presence of aqueous sodium hydroxide to form propan-1-ol.

Question 7.7 Give the structures and IUPAC names of monohydric phenols of molecular formula, $C_7 H_8 O$ .

Answer :

The structures and IUPAC names of monohydric phenols of molecular formula, $C_7 H_8 O$ .

Phenol: $C_6 H_5 OH$

$C_7 H_8 O \rightarrow (C_6 H_5 OH)(C H_2)$

Question 7.8 While separating a mixture of ortho and para nitrophenols by steam distillation, name the isomer which will be steam volatile. Give reason.

Answer :

Due to inter-molecular H bonding in para-nitrophenol, it gets tightly bonded with water. But ortho nitrophenol has intra-molecular H bonding and hence is steam volatile.

Question 7.9 Give the equations of reactions for the preparation of phenol from cumene.

Answer :

Cumene (isopropylbenzene) is oxidised in the presence of air to form cumene hydroperoxide. On treating with dilute acid it is converted to phenol and acetone.

Question 7.10 Write chemical reaction for the preparation of phenol from chlorobenzene.

Answer :

Chlorobenzene, when fused with NaOH, produces sodium phenoxide which on acidification produces Phenol.

Question 7.11 Write the mechanism of hydration of ethene to yield ethanol.

Answer :

Ethanol is yielded from ethene by acid catalysed hydration.

The mechanism:

Step 1. Protonation of alkene to form carbocation by electrophilic attack of hydronium ion.

Step 2. Nucleophilic attack of water on carbocation .

Step 3. Deprotonation to form an alcohol.

Question 7.12 You are given benzene, $conc. H_2SO_4$ and NaOH. Write the equations for the preparation of phenol using these reagents .

Answer :

When benzene reacts with $conc. \:H_2SO_4$ and heat it gives benzene sulphonic acid ,and after sulphonic this acid with NaOH then it gives phenol

Question 7.13 Show how will you synthesise:
(i) 1-phenylethanol from a suitable alkene.

Answer :

Styrene on acid catalysed hydration gives 1-phenylethanol.

Question 7.13 (2) Show how will you synthesise:(ii) cyclohexylmethanol using an alkyl halide by an $SN^{2}$ reaction.

Answer :

On adding NaOH to chloromethylcyclohexane, cyclohexy methanol is formed.

Question 7.13 Show how will you synthesise:
(iii) pentan-1-ol using a suitable alkyl halide?

Answer :

when 1-chloropentane reacts with NaOH it gives pantan-1-ol

Question 7.14 Give two reactions that show the acidic nature of phenol. Compare acidity of phenol with that of ethanol.

Answer :

1. Phenol reacts with sodium to give sodium phenoxide, liberating hydrogen gas.

2. Phenol reacts with sodium hydroxide to give sodium phenoxide and water.

Phenol is more acidic than ethanol. This is because phenol after losing a proton becomes phenoxide ion which is highly stable due to resonance whereas ethoxide ion does not.

Question 7.15 Explain why is ortho nitrophenol more acidic than ortho methoxyphenol ?

Answer :

Ortho-nitrophenol is more acidic than ortho- methoxyphenol . The presence of the nitro group, which is an electron withdrawing group, at the ortho position decreases the electron density in the O-H bond. Also, the o- nitrophenoxide ion formed after the loss of protons is stabile due to resonance. Hence, ortho nitrophenol is a stronger acid. Whereas the methoxy group is an electron-releasing group. Thus, it increases the electron density in the O-H bond.

Question 7.16 Explain how does the –OH group attached to a carbon of benzene ring activate it towards electrophilic substitution?

Answer :

The -OH group is an electron-donating group (EDG). Thus, it increases the electron density in the benzene ring in the resonance structure of phenol. As a result, the benzene ring is activated towards electrophilic substitution.

Question 7.17(i) Give equations of the following reactions:
(i) Oxidation of propan-1-ol with alkaline $KMnO_4$ solution.

Answer :

Oxidation of propane-1-ol with alkaline $KMnO_4$ solution gives propanoic acid.

$\\CH_{3}CH_{2}CH_{2}OH \rightarrow CH_{3}CH_{2}COOH\\$

Question 7.17(ii) Give equations of the following reactions:

(ii) Bromine in $CS_2$ with phenol.

Answer :

Bromine in $CS_2$ with phenol produces a mixture of o-bromo phenol and p-bromo phenol is formed.

Question 7.17(iii) Give equations of the following reactions:

(iii) Dilute HNO₃ with phenol.

Answer :

When dilute HNO₃ reacts with phenol it gives o-bromo phenol and p-bromo phenol

Question 7.17(iv) Give equations of the following reactions:
(iv) Treating phenol with chloroform in presence of aqueous NaOH.

Answer :

Treating phenol with chloroform in presence of aqueous NaOH.

This reaction is known as the Reimer-Tiemann reaction.

Question 7.18(i) Explain the following with an example.
(i) Kolbe’s reaction.

Answer :

Kolbe’s reaction: Phenol with carbon dioxide under pressure followed by treating the product with sulphuric acid produces Ortho-hydroxybenzoic acid (salicylic acid). Phenoxide ion generated is more reactive than phenol towards electrophilic aromatic substitution. Hence, it undergoes electrophilic substitution with carbon dioxide, a weak electrophile.

Question 7.18(ii) Explain the following with an example.
(ii) Reimer-Tiemann reaction.

Answer :

On treating phenol with chloroform in the presence of sodium hydroxide, a –CHO group is introduced at the ortho position of the benzene ring. This reaction is known as Reimer - Tiemann reaction

Question 7.18(iii) Explain the following with an example. (iii) Williamson ether synthesis.

Answer :

Williamson ether synthesis is a reaction forming ether from a primary alkyl halide via S_N2 reaction.

Question 7.18(iv) Explain the following with an example.(iv) Unsymmetrical ether.

Answer :

If the alkyl or aryl groups attached to the oxygen atom are different, then it is mixed or unsymmetrical ether.

Eg: $C_2H_5-O-CH_3\ and\ C_2H_5-O-C_6H_5$

Question 7.19 . Write the mechanism of acid dehydration of ethanol to yield ethene.

Answer :

Alcohols undergo dehydration (removal of a molecule of water) to form alkenes on treating with a protic acid. Ethanol undergoes dehydration by heating it with concentrated sulphuric acid at 443 K.

Question 7.20(i) How are the following conversions carried out?
(i) Propene $\rightarrow$ Propan-2-ol.

Answer :

Acid catalysed hydration of propene produces propan-2-ol.

Question 7.20(ii) How are the following conversions carried out?
(ii) Benzyl chloride $\rightarrow$ Benzyl alcohol.

Answer :

Benzyl chloride treated with NaOH followed by acidification produces benzyl alcohol.

Question 7.20(iii) How are the following conversions carried out?
(iii) Ethyl magnesium chloride $\rightarrow$ Propan-1-ol.

Answer :

Ethyl magnesium chloride treated with formaldehyde followed by hydrolysis produces propan-1-ol.

Question 7.20(iv) How are the following conversions carried out?
(iv) Methyl magnesium bromide $\rightarrow$ 2-Methylpropan-2-ol.

Answer :

Methyl magnesium bromide treated with propane, gives 2-methylpropane-2-ol on hydrolysis.

Question 7.21(i) Name the reagents used in the following reactions:
(i) Oxidation of a primary alcohol to carboxylic acid.

Answer :

Acidic/neutral/alkaline potassium permanganate $(KMnO_4)$ or acidified $K_2Cr_2O_7$

Question 7.21(ii) Name the reagents used in the following reactions:
(ii) Oxidation of a primary alcohol to aldehyde.

Answer :

The reagent used for oxidation of primary alcohol to aldehyde is Pyridinium chlorochromate (PCC) .

Question 7.21(iii) Name the reagents used in the following reactions:
(iii) Bromination of phenol to 2,4,6-tribromophenol.

Answer :

Reagents used in the bromination of phenol to 2,4,6-tribromophenol is Bromine water

Question 7.21(iv) Name the reagents used in the following reactions:

(iv) Benzyl alcohol to benzoic acid.

Answer :

Reagent used in the benzyl alcohol to benzoic acid isAcidified $KMnO_4$ (potassium permanganate)

Question 7.21(v) Name the reagents used in the following reactions:
(v) Dehydration of propan-2-ol to propene.

Answer :

Reagents used in the dehydration of propan-2-ol to propene is Concentrated Phosphoric acid.

Question 7.21(vi) Name the reagents used in the following reactions:
(vi) Butan-2-one to butan-2-ol.

Answer :

Reagent used in the butan-2-one to butan-2-ol is $LiAlH_4\ or\ NaBH_4$

Question 7.22 Give reason for the higher boiling point of ethanol in comparison to methoxymethane.

Answer :

Ethanol undergoes intermolecular hydrogen bonding due to the presence of -OH group. Therefore, extra energy is required to break those hydrogen bonds. Whereas methoxymethane does not make H-bonds and hence ethanol has a higher boiling point than methoxymethane.

Question 7.23(i) Give IUPAC names of the following ethers:

Answer :

IUPAC names of the given ether is 1-Ethoxy-2-methylpropane

Question 7.23(ii) Give IUPAC names of the following ethers:

Answer :

IUPAC names of the given ether is 2-Chloro-1-methoxyethane

Question 7.23(iii) Give IUPAC names of the following ethers:

Answer :

IUPAC names of the given ether is 4-Nitroanisole

Question 7.23(iv) Give IUPAC names of the following ethers:

Answer :

IUPAC names of the given ether is 1-Methoxypropane

Question 7.23(v) Give IUPAC names of the following ethers:

Answer :

IUPAC names of the given ether is 4-Ethoxy-1, 1-dimethylcyclohexane

Question 7.23(vi) Give IUPAC names of the following ethers:

Answer :

IUPAC names of the given ether is Ethoxybenzene

Question 7.24(i) Write the names of reagents and equations for the preparation of the following ethers by Williamson’s synthesis:
(i) 1-Propoxypropane

Answer :

Names of reagents and equations for the preparation of the 1-Propoxypropane ether by Williamson’s synthesis:-

Question 7.24(ii) Write the names of reagents and equations for the preparation of the following ethers by Williamson’s synthesis:
(ii) Ethoxybenzene

Answer :

Names of reagents and equations for the preparation of the Ethoxybenzene ether by Williamson’s synthesis:-

with NaBr as a side product.

Question 7.24(iii) Write the names of reagents and equations for the preparation of the following ethers by Williamson’s synthesis:
(iii) 2-Methoxy-2-methylpropane

Answer :

Names of reagents and equations for the preparation of the 2-Methoxy-2-methylpropane ether by Williamson’s synthesis:-

Question 7.24(iv) Write the names of reagents and equations for the preparation of the following ethers by Williamson’s synthesis: (iv) 1-Methoxyethane

Answer :

Names of reagents and equations for the preparation of the1-Methoxyethane ether by Williamson’s synthesis:-

Question 7.25 Illustrate with examples the limitations of Williamson synthesis for the preparation of certain types of ethers.

Answer :

Williamson synthesis involves $S_N2$ attack by alkoxide ion on a primary alkyl halide. But if secondary or tertiary alkyl halides are taken then alkenes would be produced because elimination would take place. This is because alkoxides are nucleophiles as well as strong bases.

Question 7.26 How is 1-propoxypropane synthesised from propan-1-ol? Write mechanism of this reaction.

Answer :

Propan-1-ol on dehydration using protic acids such as sulphuric acid gives 1-propoxypropane.

Mechanism of this reaction:

Formation of protonated alcohol.

Formation of carbocation: It is the slowest step and hence, the rate determining step of the reaction.

Formation of ethene by the elimination of a proton.

Question 7.27 Preparation of ethers by acid dehydration of secondary or tertiary alcohols is not a suitable method. Give reason.

Answer :

The formation of ethers by dehydration of a primary alcohol is an S_N2 reaction. In case of secondary or tertiary alcohols, the alkyl group is hindered and hence elimination dominates substitution. Therefore alkenes are formed in place of ethers.

Question 7.28(i) Write the equation of the reaction of hydrogen iodide with:
(i) 1-propoxypropane

Answer :

1-propoxypropane reacts with HI to give propan-1-ol and 1-iodopropane as the products.

Question 7.28(ii) Write the equation of the reaction of hydrogen iodide with: (ii) methoxybenzene

Answer :

Methoxybenzene reacts with HI to give phenol and iodomethane.

Question 7.28(iii) Write the equation of the reaction of hydrogen iodide with: (iii) benzyl ethyl ether.

Answer :

Benzyl ethyl ether reacts with HI to give benzyl iodide and ethanol.

Question 7.29(i) Explain the fact that in aryl alkyl ethers (i) the alkoxy group activates the benzene ring towards electrophilic substitution

Answer :

Due to the +R effect of the alkoxy group, it increases the electron density of the benzene ring pushing electrons into the ring making the benzene ring activated towards electrophilic substitution reactions.

Question 7.29(ii) Explain the fact that in aryl alkyl ethers (ii) it directs the incoming substituents to ortho and para positions in benzene ring.

Answer :

The above resonating structures shows that the electron density increases more at the ortho and para positions as compared to the meta positions. Hence, the alkoxy group directs the incoming substituents to ortho and para positions in the benzene ring.

7.30. Write the mechanism of the reaction of HI with methoxymethane.

Answer :

Following is the mechanism:

1. Protonation of methoxymethane

2. Nucleophilic attack of $I^-$

3. If HI is in excess, then methanol formed in step 2 reacts with another HI molecule and gets converted to methyl iodide at a high temperature.

Question 7.31(i) Write equations of the following reactions:
(i) Friedel-Crafts reaction – alkylation of anisole.

Answer :

Fridel Craft reaction(Alkylation):

Question 7.31(ii) Write equations of the following reactions: (ii) Nitration of anisole.

Answer :

Nitration of anisole:

Question 7.31(iii) Write equations of the following reactions: (iii) Bromination of anisole in ethanoic acid medium.

Answer :

Bromination of anisole in ethanoic acid medium:

Question 7.31(iv) Write equations of the following reactions: (iv) Friedel-Craft’s acetylation of anisole.

Answer :

Friedel-Craft’s acetylation of anisole:

Question 7.32 Show how would you synthesise the following alcohols from appropriate alkenes?

Answer :

(i)

(ii)

(iii)

(iv)

Question 7.33 When 3-methylbutan-2-ol is treated with HBr, the following reaction takes
place:

Give a mechanism for this reaction.
(Hint : The secondary carbocation formed in step II rearranges to a more stable tertiary carbocation by a hydride ion shift from 3rd carbon atom.

Answer :

Mechanism for the reaction 3-methylbutan-2-ol is treated with HBr