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Hydrocarbons Class 11th Notes - Free NCERT Class 11 Chemistry Chapter 13 Notes - Download PDF

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Hydrocarbons Class 11th Notes - Free NCERT Class 11 Chemistry Chapter 13 Notes - Download PDF

Edited By Sumit Saini | Updated on Apr 26, 2022 01:59 PM IST

NCERT Class 11 Chemistry chapter 13 notes based on recognising the structure and IUPAC names of hydrocarbons also how they are prepared. The chapter Hydrocarbons Class 11 notes also differentiate the conformations of ethane and also the application of hydrocarbons. Here in this NCERT chapter 13 Class 11 makes prediction easier to find the additional products of alkenes and alkynes which are unsymmetrical.

Introductory Part may include: The NCERT Class 11 chapter 13 notes structure of benzene, electrophilic substitution and carcinogenicity are the highlighting key feature of Hydrocarbons 11th Notes. CBSE Class 11 Chemistry chapter 13 notes also covers the basic equations as well as the substitution reactions which includes some name reactions, and points to be ponder such as aromaticity, Huckle’s rule, Preparation of benzene which is required for the deep knowledge to score good in the examination purposes. All these topics are available easily and can be downloaded from Class 11 Chemistry chapter 13 notes pdf download.

Also, students can refer,

NCERT Class 11 Chapter 13 Notes

Discussing the Main Terms Related to Hydrocarbon:

  • Hydrocarbon:

Compounds formed with the help of carbon and hydrogen are known as Hydrocarbons.

  • Saturated hydrocarbon:

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Saturated hydrocarbons are those which contains single bond in between two carbon atoms. Example: methane

  • Unsaturated hydrocarbon:

The hydrocarbon with double or triple bonds other than single bond is so called unsaturated hydrocarbons. Example: ethyne, ethene.

  • Aromatic Hydrocarbon:

The aromatic hydrocarbon is defined as compounds of benzene and their derivatives.

Example: Benzene and Aniline.

  • Alicyclic compounds:

The cyclic ring only consisting of carbon atoms are called alicyclic compounds.

Example:

  • Heterocyclic compounds:

The cyclic ring of such compound is composed of carbon as well as other than carbon atom.

Example:

  • Alkanes:

Simplest form of organic compound that are made up of carbon and hydrogen. Carbon atoms are made up of single bond; covalent. As the chain of carbon is composed of single bonds only so they are fully saturated hydrocarbons. This class of alkanes are chemically inert in nature, so they are called paraffins.

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Guidelines for Writing Names (Nomenclature):

We proceed further with steps to understand the IUPAC nomenclature or how to write structural formula of different hydrocarbons.

Step1. First to identify the longest chain among all the carbon.

Step2. In the second step give number to the selected chain. Try to give the number from left to right. As this should also be in mind that lowest numbers attached to alkyl group comes first.

Step3. Identifying the alkyl group attached to main chain.

Step4. Finally writing the IUPAC names.

Newman Projections:

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Relative stability of conformations:

The two forms, which decides the stability and energy of the molecule. When the alkane(ethane) is present in staggered form than, maximum repulsion occur, which creates minimum energy and maximum in stability. Whereas in eclipsed form of ethane the stability reduces as the electrons of carbon cloud and hydrogen clouds come closer and it posses more energy than staggered form, thus the stability in this form reduces.

  • Alkenes:

The carbon that contains double bond in it are alkene with general formula CnH2n.

Points to remember while writing the formula for alkenes:

  1. Two bonds are present here in alkenes in which one is sigma and other is pi bond.

  2. The availability of number of electrons in alkenes are higher so they are more reactive than alkanes.

Nomenclature for alkenes:

For writing the names of alkenes the same steps should be followed up which we studied in the earlier sections of nomenclature, where the parent or main chain is the longest one and indication of number started from one end.

If in case in one chain two or more double bonds are present than diene suffix should be used for it.

Isomerism:

Basically, we go through with different types of isomerism, some of them are listed below.

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  1. Structural Isomerism:

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  1. Geometrical Isomerism:

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  • Alkynes:

Alkynes are the chain of carbon having triple bonds with general formulaCnH2n-2.

Important member of alkyne group of hydrocarbon is acetylene.

Points to remember while writing the formula for alkenes:

  1. In this triple bond two of them are pi bonds and one is sigma bond.

  2. Similar to alkenes, the pi electrons are found more, so they will go in addition reaction.

Nomenclature for Alkynes:

For writing the names of alkenes the same steps should be followed up which we studied in the earlier sections of nomenclature, where the parent or main chain is the longest one and indication of number started from one end.

While writing the names of alkyne hydrocarbon we use suffix as yne and first numbering the carbon which is attached to triple bond.

Preparation of alkynes:

From calcium carbide: By treating calcium carbide with water formation of ethyne can be possible.

From vicinal dihalides: Dehydrohalogenation occur alcoholic potassium

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Aromatic Hydrocarbons:

The important feature of aromatic hydrocarbon is that most of the compounds containing the benzene ring and are also called arenes. The compounds having benzene rings are called benzenoids and those who have to benzene ring in their structure are termed as non-benzenoids.

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Above mentioned are the examples of Hydrocarbon.

Nomenclature of aromatic compounds:

The common names as according to IUPAC is accepted for naming the benzene and its homologous.

Structure of benzene:

The molecular formula of writing benzene is C6H6, and are highly unsaturated compounds.

According to Kekule’s , he had given benzene structure in the year1865, in that he showed single and double bonds are present on alternate positions in the ring.

He also gave that benzene ring would present in two forms.

Failure’s of Kekule’s benzene ring:

He wont able to explain how the stability of benzene ring can be achieved and also why the substitution reactions are preferred than addition reactions.

Resonance structure:

Resonance is defined as the where we can make two or more structures for the same compound and the atoms in that are also identical such structure is termed as Resonance structure.

Below showing you the resonance structure of benzene.

Orbital structure:

S-orbitals of hydrogen atom in Benzene ring form sigma bonds with carbon in condition of overlapping of hybrid orbitals.

Important points to remember:

  • Benzene is found as planar in structure and this can be detected by the technique called X-ray diffractions.

  • The bond length of carbon-carbon (139) which is intermediated between C-C of bond length(133pm) and C-C of bond length (154) is of same bond order. So, under normal benzene will go for addition reactions, which is the unusual behaviour of benzene.

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Aromaticity:

This is the property of sp2 hybridized planar rings, where p orbitals allow cyclic delocalization of pi electrons.

Huckle’s Rule:

When cyclic pi electron cloud overlap, with p orbitals which contains(4n+2) pi electrons, such rule is termed as Huckle rule. Here n denotes the positive integer and 0.

Preparation of Benzene using different methods and compounds:

  • It can be prepared commercially by isolating coal tar.

  • There are some of the synthetic methods through which we can prepare the benzene.

  • The synthetic methods are listed below:

Physical Properties:

  • Colourless liquid.

  • Insoluble in water.

  • Soluble in alcohol, ether, etc.

  • Good solvent for organic and inorganic substances.

  • Sooty flame with blue in colour.

Chemical Properties:

  • To show the chemical properties of benzene it must go through some reactions.

  • Addition reaction

  • Electrophilic substitution reaction

  • Synthetic Methods:

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Electrophilic Substitution Reactions is as Follows:

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Friedel-Crafts Alkylation Reaction:

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Mechanism Related with Electrophilic Substitution Reaction:

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Steps included in the mechanism of electrophilic substitution reactions:

Step1: In the first step formation of electrophile occur.

Step2: To form the carbonium ion electrophile needs to attack on aromatic ring.

Step3: Loss in number of proton gives us the substitution product.

Carcinogenicity and Toxicity:

Some of the polynuclear hydrocarbons contains benzene rings more than two in its chain, and when they fused together they produce property which creates cancer.

They are formed by the incomplete combustion of tobacco, coal, etc.

Examples are as follows:

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Activating Groups and Deactivating Groups:

The activating groups are those who activate the benzene ring to attack with the help of an electrophile.

Deactivating groups are those who due to strong -I effect are formed which decreases the overall density and makes substitution difficult.

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Meta-Directing Groups:

These are the groups who helps to direct the incoming group to meta position are termed as meta-directing groups.

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Significance of NCERT Class 11 Chemistry Chapter 13 Notes

Hydrocarbons Class 11 notes, will be helpful in revising the chapter and to cover the main topics more precisely and conveniently. The CBSE Class 11 Chemistry chapter 13 notes helps to understand the nomenclature and structures of different compounds. Hydrocarbons Class 11 notes guide is a perfect guide to help to get a good score in CBSE board examination and to prepare offline. Class 11 Hydrocarbon notes contain the structure of different types of aromatic compounds, their reactions (electrophilic substitution, addition) and also the properties.

NCERT Class 11 Notes Chapter-Wise

Subject Wise NCERT Exemplar Solutions

Subject Wise NCERT Solutions

Frequently Asked Question (FAQs)

1. In Class 11 Chemistry chapter 13, we studied about alkene so how will we separate propene from propyne?

When propyne reacts with ammoniacal mixture.

2. To distinguish between ethene and ethyne in Class 11 Chemistry chapter 13 which two reagents were used?

CuCl solution and ammoniacal 

3. In states of matter Class 11 notes, we studied the properties than how the branching of alkane effects the boiling point?

It will decreases the boiling point.

4. According to NCERT notes for Class 11 Chemistry chapter 13, what are two industrial sources where hydrocarbons are used?

Petroleum

Coal

These topics can also be downloaded from Hydrocarbons class 11 notes pdf download.

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A block of mass 0.50 kg is moving with a speed of 2.00 ms-1 on a smooth surface. It strikes another mass of 1.00 kg and then they move together as a single body. The energy loss during the collision is

Option 1)

0.34\; J

Option 2)

0.16\; J

Option 3)

1.00\; J

Option 4)

0.67\; J

A person trying to lose weight by burning fat lifts a mass of 10 kg upto a height of 1 m 1000 times.  Assume that the potential energy lost each time he lowers the mass is dissipated.  How much fat will he use up considering the work done only when the weight is lifted up ?  Fat supplies 3.8×107 J of energy per kg which is converted to mechanical energy with a 20% efficiency rate.  Take g = 9.8 ms−2 :

Option 1)

2.45×10−3 kg

Option 2)

 6.45×10−3 kg

Option 3)

 9.89×10−3 kg

Option 4)

12.89×10−3 kg

 

An athlete in the olympic games covers a distance of 100 m in 10 s. His kinetic energy can be estimated to be in the range

Option 1)

2,000 \; J - 5,000\; J

Option 2)

200 \, \, J - 500 \, \, J

Option 3)

2\times 10^{5}J-3\times 10^{5}J

Option 4)

20,000 \, \, J - 50,000 \, \, J

A particle is projected at 600   to the horizontal with a kinetic energy K. The kinetic energy at the highest point

Option 1)

K/2\,

Option 2)

\; K\;

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zero\;

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In the reaction,

2Al_{(s)}+6HCL_{(aq)}\rightarrow 2Al^{3+}\, _{(aq)}+6Cl^{-}\, _{(aq)}+3H_{2(g)}

Option 1)

11.2\, L\, H_{2(g)}  at STP  is produced for every mole HCL_{(aq)}  consumed

Option 2)

6L\, HCl_{(aq)}  is consumed for ever 3L\, H_{2(g)}      produced

Option 3)

33.6 L\, H_{2(g)} is produced regardless of temperature and pressure for every mole Al that reacts

Option 4)

67.2\, L\, H_{2(g)} at STP is produced for every mole Al that reacts .

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Option 1)

0.02

Option 2)

3.125 × 10-2

Option 3)

1.25 × 10-2

Option 4)

2.5 × 10-2

If we consider that 1/6, in place of 1/12, mass of carbon atom is taken to be the relative atomic mass unit, the mass of one mole of a substance will

Option 1)

decrease twice

Option 2)

increase two fold

Option 3)

remain unchanged

Option 4)

be a function of the molecular mass of the substance.

With increase of temperature, which of these changes?

Option 1)

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Option 2)

Weight fraction of solute

Option 3)

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Option 4)

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Number of atoms in 558.5 gram Fe (at. wt.of Fe = 55.85 g mol-1) is

Option 1)

twice that in 60 g carbon

Option 2)

6.023 × 1022

Option 3)

half that in 8 g He

Option 4)

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A pulley of radius 2 m is rotated about its axis by a force F = (20t - 5t2) newton (where t is measured in seconds) applied tangentially. If the moment of inertia of the pulley about its axis of rotation is 10 kg m2 , the number of rotations made by the pulley before its direction of motion if reversed, is

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less than 3

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more than 6 but less than 9

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more than 9

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Vlogger

In a career as a vlogger, one generally works for himself or herself. However, once an individual has gained viewership there are several brands and companies that approach them for paid collaboration. It is one of those fields where an individual can earn well while following his or her passion. 

Ever since internet costs got reduced the viewership for these types of content has increased on a large scale. Therefore, a career as a vlogger has a lot to offer. If you want to know more about the Vlogger eligibility, roles and responsibilities then continue reading the article. 

3 Jobs Available
Editor

Individuals in the editor career path is an unsung hero of the news industry who polishes the language of the news stories provided by stringers, reporters, copywriters and content writers and also news agencies. Individuals who opt for a career as an editor make it more persuasive, concise and clear for readers. In this article, we will discuss the details of the editor's career path such as how to become an editor in India, editor salary in India and editor skills and qualities.

3 Jobs Available
Advertising Manager

Advertising managers consult with the financial department to plan a marketing strategy schedule and cost estimates. We often see advertisements that attract us a lot, not every advertisement is just to promote a business but some of them provide a social message as well. There was an advertisement for a washing machine brand that implies a story that even a man can do household activities. And of course, how could we even forget those jingles which we often sing while working?

2 Jobs Available
Photographer

Photography is considered both a science and an art, an artistic means of expression in which the camera replaces the pen. In a career as a photographer, an individual is hired to capture the moments of public and private events, such as press conferences or weddings, or may also work inside a studio, where people go to get their picture clicked. Photography is divided into many streams each generating numerous career opportunities in photography. With the boom in advertising, media, and the fashion industry, photography has emerged as a lucrative and thrilling career option for many Indian youths.

2 Jobs Available
Social Media Manager

A career as social media manager involves implementing the company’s or brand’s marketing plan across all social media channels. Social media managers help in building or improving a brand’s or a company’s website traffic, build brand awareness, create and implement marketing and brand strategy. Social media managers are key to important social communication as well.

2 Jobs Available
Welding Engineer

Welding Engineer Job Description: A Welding Engineer work involves managing welding projects and supervising welding teams. He or she is responsible for reviewing welding procedures, processes and documentation. A career as Welding Engineer involves conducting failure analyses and causes on welding issues. 

5 Jobs Available
QA Manager
4 Jobs Available
Product Manager

A Product Manager is a professional responsible for product planning and marketing. He or she manages the product throughout the Product Life Cycle, gathering and prioritising the product. A product manager job description includes defining the product vision and working closely with team members of other departments to deliver winning products.  

3 Jobs Available
Quality Controller

A quality controller plays a crucial role in an organisation. He or she is responsible for performing quality checks on manufactured products. He or she identifies the defects in a product and rejects the product. 

A quality controller records detailed information about products with defects and sends it to the supervisor or plant manager to take necessary actions to improve the production process.

3 Jobs Available
Production Manager
3 Jobs Available
Procurement Manager

The procurement Manager is also known as  Purchasing Manager. The role of the Procurement Manager is to source products and services for a company. A Procurement Manager is involved in developing a purchasing strategy, including the company's budget and the supplies as well as the vendors who can provide goods and services to the company. His or her ultimate goal is to bring the right products or services at the right time with cost-effectiveness. 

2 Jobs Available
Process Development Engineer

The Process Development Engineers design, implement, manufacture, mine, and other production systems using technical knowledge and expertise in the industry. They use computer modeling software to test technologies and machinery. An individual who is opting career as Process Development Engineer is responsible for developing cost-effective and efficient processes. They also monitor the production process and ensure it functions smoothly and efficiently.

2 Jobs Available
Merchandiser
2 Jobs Available
AWS Solution Architect

An AWS Solution Architect is someone who specializes in developing and implementing cloud computing systems. He or she has a good understanding of the various aspects of cloud computing and can confidently deploy and manage their systems. He or she troubleshoots the issues and evaluates the risk from the third party. 

4 Jobs Available
QA Manager
4 Jobs Available
Azure Administrator

An Azure Administrator is a professional responsible for implementing, monitoring, and maintaining Azure Solutions. He or she manages cloud infrastructure service instances and various cloud servers as well as sets up public and private cloud systems. 

4 Jobs Available
Information Security Manager

Individuals in the information security manager career path involves in overseeing and controlling all aspects of computer security. The IT security manager job description includes planning and carrying out security measures to protect the business data and information from corruption, theft, unauthorised access, and deliberate attack 

3 Jobs Available
Computer Programmer

Careers in computer programming primarily refer to the systematic act of writing code and moreover include wider computer science areas. The word 'programmer' or 'coder' has entered into practice with the growing number of newly self-taught tech enthusiasts. Computer programming careers involve the use of designs created by software developers and engineers and transforming them into commands that can be implemented by computers. These commands result in regular usage of social media sites, word-processing applications and browsers.

3 Jobs Available
Product Manager

A Product Manager is a professional responsible for product planning and marketing. He or she manages the product throughout the Product Life Cycle, gathering and prioritising the product. A product manager job description includes defining the product vision and working closely with team members of other departments to deliver winning products.  

3 Jobs Available
ITSM Manager
3 Jobs Available
.NET Developer

.NET Developer Job Description: A .NET Developer is a professional responsible for producing code using .NET languages. He or she is a software developer who uses the .NET technologies platform to create various applications. Dot NET Developer job comes with the responsibility of  creating, designing and developing applications using .NET languages such as VB and C#. 

2 Jobs Available
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