Shake well before use, You may have noticed this line many times on juice or medicine bottles. It was written because they are suspensions. It is a mixture where small particles are mixed in a liquid, but they remain undissolved. If the mixture is set aside for some time, the particles settle at the bottom of the container. We notice the phenomenon of suspension every day around us, like your favourite chocolate milk where chocolate settles at the bottom of the container after some time, orange juice with pulp, muddy water, and lemonade with lemon pulp. It is a heterogeneous mixture in which solute particles don't dissolve but rather remain suspended in the medium's bulk. The size of particles in the suspension solution is at least 100 times that of the solution particles.
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Suspension is commonly used in:
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Oral suspension
The oral suspension means suspension for oral delivery, made up of undissolved particles of one or more medicinal substances combined with a liquid carrier
Colloids
|
Suspension
| |
Type
| It is homogeneous. | It is heterogeneous. |
Particle size of suspension | The size of the particle is between 2 nm to 1000 nm. | The size of the particle is larger than 1000 nm. |
Visibility | The particle can’t be seen by a low microscope | The particle can be seen with a low microscope |
Flocculated suspension
A flocculated suspension is one in which the suspension's particles have been flocculated. A flocculated suspension is made up of big particles (flocks) that cause fast sedimentation. Sedimentation is the process of aggregates or suspended particles settling to the bottom of a liquid. Particles clump together to form massive aggregates that can act as large individual particles. A significant number of particles settle down when these aggregates settle down. Then the sedimentation rate is high. Floccules are the name for these aggregates. Under the influence of gravity, floccules can settle faster than smaller particles.
Deflocculated suspension
A deflocculated suspension is one in which there has been no flocculation. Single particles take on the role of individual particles in this scenario. These tiny particles sink when sedimentation occurs. Dispersed particles exist as distinct entities in a deflocculated suspension. The sedimentation rate is slow because tiny particles settle more slowly than huge floccules. In comparison to a flocculated suspension, the resulting sediment has a modest volume. The supernatant of this suspension will remain cloudy even after the sediment has formed. Caking is a term used to describe the sediment development in this area.
Difference between flocculated and deflocculated suspension
Flocculated suspension
|
Deflocculated suspension
|
Pleasant appearance due to particle dispersion that is homogenous. | Sediment that is a little unattractive. |
The supernatant is still hazy. | The supernatant is visible. |
Particles are self-contained entities. | Particles clump together to form loose aggregates. |
Since the particles are tiny, the rate of sedimentation is sluggish. | Since flocs are a cluster of tiny particles with a larger size, the rate is high. |
Particles settle separately and independently. | Particles form flocs as they settle. |
The sedimentation is densely packed, resulting in a firm cake. | Sediment is a loosely packed network that cannot form a firm cake. |
It is impossible to re-disperse the hard cake. | The sediment is easily redistributed. |
Due to the increased specific surface area, bioavailability is higher. | Due to the tiny specific surface area, bioavailability is low. |
A pharmaceutical suspension is a finely split insoluble substance suspended in a liquid medium in a coarse dispersion of biphasic liquid dose form.
Types of Pharmaceutical Suspension
Suspension features and general characteristics are described below -
The solvent is the component of the solution that dissolves the other component, whereas the solute is the component that is dissolved in the solvent. In general, the amount of solute in a solution is smaller than the amount of solvent.
Solution examples
Properties of true solution
The following properties are:
Types of true solutions
Depending upon the amount of solute present in a solution, it can be classified as dilute, concentrated, or a saturated solution. A solution that contains a relatively larger amount of solute is a concentrated solution, while a solution that contains a relatively smaller amount of solute is a dilute solution.
A colloid is a heterogeneous mixture in which particles are evenly distributed throughout the fluid. It is also known as a colloidal solution. The term colloid is occasionally used to refer to the dispersed component in a colloidal solution alone, but colloidal suspension clearly refers to the entire mixture. Despite the fact that suspension and colloidal suspension (solution) are both forms of mixtures. Because of the smaller particle size than the suspension, it seems to be homogeneous, and the Tyndall effect is also demonstrated.
Colloidal properties
A colloid is a heterogeneous mixture with colloidal particles that are invisible to the human eye.
Dispersed phase particles in colloids have a diameter of 1–100 nm (approximately).
They demonstrate Tyndall's effect.
When dispersed particles in colloids are left undisturbed, they do not settle down.
Colloids are mixes that are stable.
The dispersed phase and the dispersion medium in colloids cannot be separated by filtration.
Brownian movement is shown by the dispersed particles.
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Components of a colloidal solution
A colloidal solution comprises two components: the dispersed phase and the dispersing medium. The dispersed phase of a colloidal solution is the solute-like component, while the dispersing medium is the solvent-like component. Solid, liquid, or gas can be used as the dispersed phase and dispersing medium.
Forms of colloidal solution
Colloids are divided into two categories based on their constituents: dispersed phase and dispersing medium.
Gas as a dispersing medium
Related Topics link, |
Aerosol: Aerosol is a mixture that is formed when solid or liquid particles are dispersed in a gaseous medium. For instance, cloud, smog, and smoke.
Liquid and solid aerosols are the two forms of aerosols.
Liquid as a dispersing medium
Solid as a dispersing medium
Dispersed medium |
Dispersed phase |
Type |
Phase |
Gas
| Liquid | Aerosol | Fog |
Liquid | Gas | Aerosol | Smoke |
Liquid | Gas | Foam | Shaving cream |
Liquid | Liquid | Emulsion | Milk |
Liquid | Solid | Sol | Mud |
Solid | Gas | Foam | Sponge, cake |
Solid | Liquid | Gel | Cheese |
Solid | Solid | Solid sol | Colored gemstone, glasses |
(Self-created)
It can be used to determine if the solution is a colloid. When a beam of light is passed through a colloid, it is not allowed to completely pass through the colloidal particles present in the solution. When compared to red light, blue light is scattered to a greater extent. This is due to the fact that blue light has a shorter wavelength than red light. This is why the smoke emitted by motorcycles might appear blue at times.
Examples of the Tyndall Effect
The Tyndall Effect can be seen in milk, which is a colloid that contains fat and protein globules. In a foggy environment, when a torch is turned on, the light's path becomes visible.
Difference between Solution Suspension and Colloids
Property
|
Suspension
|
Colloids
|
Solution
|
Particle size
| > 100 nm | Between 1 to 100 nm | < 100 nm |
Homogeneous/ Heterogeneous | Homogeneous | Homogeneous | Homogeneous |
Tyndall Effect | Shows effect | Shows | Does not show |
Brownian movement | May show | Shows | Do not show (mostly) |
Appearance | Opaque | Transparent | Transparent |
Settling of particles | Settles on their own | Settle on centrifugation | Do not settle |
Method of separation | Can be separated by physical methods such as filtration | Cannot be separated by physical methods | Cannot be separated by a physical method |
Stability | Unstable | Stable | Stable |
Examples | Flour and water mixture | Smoke, cheese | Sugar and water solution |
(Self-created)
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NCERT Chemistry Notes:
A suspension is a heterogeneous mixture in which solid particles are dispersed throughout a liquid or gas but are not dissolved. Over time, the solid particles tend to settle at the bottom, resulting in a separation of the mixture. Common examples include muddy water and salad dressings that separate when left standing.
The main difference between them is the size of solute particles. In solutions, there are micro particles that dissolve completely in the solvent, forming a homogeneous solution, while in suspension, the size of solute particles is very large and the particles do not dissolve in the solution, making the heterogeneous mixture.
Some examples of suspensions are:
Methods of separation of suspensions are:
Viscosity helps in maintaining suspension by influencing how the solid particles interact with the liquid. Greater viscosity helps in preventing sedimentation by providing more resistance against the motion of particles, allowing them to remain suspended for a long time.
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Correct Answer: Stagnation in economic development
Solution : The immediate consequence of the suspension of Five-year Plans in India was stagnation in economic development, as the planning process was integral to the country's development strategy.
Correct Answer: It hindered long-term economic planning.
Solution : A major criticism of the suspension of Five-year Plans in India was that it hindered long-term economic planning, disrupting the systematic approach to development that the plans aimed to provide.
Correct Answer: Poverty alleviation
Solution : After the suspension of the planning process, the Sixth Five-year Plan in India focused on poverty alleviation, aiming to improve the living standards of the country's poorest citizens.
Correct Answer: To focus on short-term economic stabilization
Solution : The primary objective of the annual plans implemented during the suspension of the Five-year Plans in India was to focus on short-term economic stabilization, addressing immediate challenges and maintaining continuity in development efforts.
Correct Answer: Political instability
Solution : The primary reason for the suspension of the Five-year Plans in India during the late 1960s was political instability, including internal conflicts and challenges faced by the government, which disrupted the planning process.