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Variable Valency - Definition, Examples, Elements, FAQs

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Variable Valency - Definition, Examples, Elements, FAQs

Edited By Team Careers360 | Updated on Jul 12, 2022 03:35 PM IST

In nature, elements rarely exist alone; instead, they interact with one another. The ability of one element to combine with another is known as valency. To achieve a stable state, elements interact with one another. It establishes the maximum amount of electrons an element can take or donate in order to form a stable electronic state.

Define Variable Valency

An element's valency is its ability to combine with other elements. The valency of an element is the amount of electrons provided or absorbed by an atom in order for it to have the electronic configuration of the nearest noble gas.

Valency Varieties:

1. Ionic compounds' valency

2. Covalent substances' valency

3. Variable valency

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Variable Valency

Variable valency is shown by some items have more than one sort of valency. These compounds have one valency in one compound different valency in another. For example, iron has a valency of 2 in some compounds, such as ferrous sulphate (FeSO4), and a valency of 3 in others, such as ferric chloride (FeCl3). There are two sorts of valencies in copper: 1 and 2. Mercury has two valency types: 1 and 2.

What is Variable Valency?

The valency of the same element might alter due to different conditions in which a chemical reaction takes place. As a result, metals such as lead, tin, copper, mercury, iron, and others have varying valency. Metals donate electrons from their valence shell to generate positively charged ions in most cases. Some metals, on the other hand, lose electrons from the shell next to the valence shell. The element has more than one electropositive valency in this case. Variable valency is a term used to describe such elements with variable valency. Valency of mercury or Valency of Hg is +1 an +2.

Why do Elements Exhibit Variable Valency?

Consider the following iron example:

Iron is a metal (Fe)

Iron has an atomic number of 26.

Electronic configuration of iron = 1s2 2s2 2p6 3s2 3p6 4s2 3d6

The electrical arrangement of 4s2 3d6 makes iron an unstable molecule. The two electrons in the 4s orbital will be eliminated first. Then iron's electrical configuration changes to 4S0 3d6. The electronic configuration 3d6 is not stable.

The d subshell will become a half-filled subshell after losing one electron. This 3d5 electronic arrangement is stable. As a result, the element iron has two and three valencies. Iron variable valencies are the names given to these valencies. To achieve stability, the elements have varying valency. The half-filled subshell has greater exchange energy, lowering the compound's energy even further.

As a result, the compound is more stable.

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Elements Having Variable Valency

Valency of cupric which is valency of Cuprous or cuprous valency (Cu+2) and cupric (Cu+3) are two types of copper (Cu).

Iron (Fe) is divided into two types: ferrous (Fe+2) and ferric (Fe+3).

Mercurous (Hg +1) and mercuric (Hg +2) are two types of mercury.

Argentous (Ag+1) and argentic (Ag+2) are two types of silver (Ag).

Stannous (Sn+2) and Stannic (Sn+3) are synonyms for Stannum (Sn).

The element with the lowest valency will be suffixed with the word "ous." The element with the highest valency will be suffixed with "ic."

Variable Electrovalency

The number of electrons lost or acquired by an element's atom during the creation of ionic bonds is its electrovalency. Variable valency is not displayed in the s-block elements. P-block elements with higher atomic numbers and inner transition elements, on the other hand, have variable valency.

There are two basic reasons why variable valency is seen

  1. The effect of an inert pair in p-block elements.

  2. In transition elements, there is a small energy difference between ns and (n-1)d sub shells, and ns and (n-2) sub shells in inner transition elements.

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NCERT Chemistry Notes:

Determination of Elements' Valencies from Compound Formulas

We know that chlorine (Cl) has a valency of 1.

The valency of sodium (Na) in sodium chloride (NaCl) is 1.

Calcium (Ca) has a valency of 2 in calcium chloride (CaCl2).

The valency of iron (Fe) in ferric chloride (FeCl3) is 3.

The valency of phosphorus (P) in phosphorus trichloride (PCl3) is 3.

The preceding example proposes a simple rule for assessing the valency of components in two-element compounds.

The number of valency units in all the atoms of one element equals the number of valency units in all the atoms of all the other elements.

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Frequently Asked Question (FAQs)

1. What is the difference between valency and variable valency?

The valence of an element is its ability to combine with other elements. The capacity of some elements to interact with other elements varies depending on the nature of the interaction; this trait is known as variable valence. For example, iron (Fe) can have valences of 2 and 3.

2. What causes variable valency in the first place?

Valence electrons are electrons that are present in an atom's outermost shell. As a result, one or more electrons from the core's outermost shell may be lost when valence electrons are removed. As a result, such items have variable valentia, indicating that they have two or more different valencies.

3. What is an example of variable valency?

Depending on the nature of the reaction, some elements combine with other atoms to donate, take, or exchange electrons in varying amounts. For starters, both ferrous and ferric oxide are formed when iron reacts with oxygen. It's known as the valence element.

4. What is the oxygen valency?

The valence value of oxygen is 2. It is an octet since it is 2,6 and only requires 2 more electrons to finish. Even though valence is equal to n for elements with n= 1,2,3, and 4 electrons in the outer shell, valence is equal to 8-n for elements with n= 5,6, and 7 electrons in the outer shell.

5. Why does phosphorus exhibit a wide range of valencies?

Because the phosphorus valence is 3, they will increase their valence due to the unoccupied d orbital. Because phosphorus has a valence shell with 5 electrons, the answer should be 3. As a result, it absorbs 3 electrons and completes its bit, because accepting 3 electrons is considerably easier than giving 5 electrons.

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